Competition of anchoring groups in adsorption on gold electrodes—a comparative spectroelectrochemical study of 4-mercaptobenzonitrile and aromatic nitriles
作者： Rudolf Holze
DOI: 10.1007/S10008-013-2076-5
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摘要: The adsorption of 4-mercaptobenzonitrile (MBN) on a polycrystalline gold electrode has been studied in spectroelectrochemical approach; results are compared with those similar study the benzonitrile and bencylcyanide. Results imply MBN via sulfur atom; case latter, compounds nitrogen atom cyano-group is found. In MBN, electron-withdrawing causes substantial weakening MBN–gold interaction.
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