Ceria maintains smaller metal catalyst particles by strong metal-support bonding
作者： J. A. Farmer , C. T. Campbell
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摘要: The energies of silver (Ag) atoms in Ag nanoparticles supported on different cerium and magnesium oxide surfaces, determined from previous calorimetric measurements of metal adsorption energies, were analyzed with respect to particle size. Their stability was found to increase with particle size below 5000 atoms per particle. Silver nanoparticles of any given size below 1000 atoms had much higher stability (30 to 70 kilojoules per mole of silver atoms) on reduced CeO2 (111) than on MgO (100). This effect is the result of the very large …
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