Revising the Subsystem Nurse's A-Phase-Silicocarnotite within the System Ca₃(PO₄)₂-Ca₂SiO₄.

作者: Patricia Ros-Tárraga , Patricia Mazón , Luis Meseguer-Olmo , Piedad De Aza

DOI: 10.3390/MA9050322

关键词:

摘要: The subsystem Nurse's A-phase-silicocarnotite within the system Ca₃(PO₄)₂-Ca₂SiO₄ was conducted as a preliminary step toward obtaining new biomaterials with controlled microstructures. Phase composition of resulting ceramics studied by X-ray diffraction, differential thermal analysis, and scanning electron microscopy attached wavelength dispersive spectroscopy. results showed that sub-system presents an invariant eutectoid point at 1366 ± 4 °C 59.5 wt % Ca₃(PO₄)₂ 40.5 Ca₂SiO₄, typical microstructure lamellae morphology. These are in disagreement previous reported data, which locate 1250 20 55 45 Ca₂SiO₄. In addition, cell attachment testing material supported mesenchymal stem adhesion spreading, cells established close contact ceramic after 28 days culture. findings indicate morphology possesses good bioactivity biocompatibility might be promising bone implant material.

参考文章(25)
GJ Lugo, P Mazón, PN De Aza, None, Phase transitions in single phase Si–Ca–P-based ceramic under thermal treatment Journal of The European Ceramic Society. ,vol. 35, pp. 3693- 3700 ,(2015) , 10.1016/J.JEURCERAMSOC.2015.04.036
Gerardo J. Lugo, Patricia Mazón, Piedad N. De Aza, Material processing of a new calcium silicophosphate ceramic Ceramics International. ,vol. 42, pp. 673- 680 ,(2016) , 10.1016/J.CERAMINT.2015.08.164
Gerardo J. Lugo, Patricia Mazón, Carmen Baudin, Piedad N. De Aza, Nurse′s A‐Phase: Synthesis and Characterization in the Binary System Ca2SiO4–Ca3(PO4)2 Journal of the American Ceramic Society. ,vol. 98, pp. 3042- 3046 ,(2015) , 10.1111/JACE.13747
H. H. Frank, M. A. Bredig, E. Kanert, Untersuchungen Über Kalk‐Alkali‐Phosphate. II. Über Calcium‐Kalium‐Phosphate Zeitschrift für anorganische und allgemeine Chemie. ,vol. 237, pp. 49- 78 ,(1938) , 10.1002/ZAAC.19382370106
Isabel M. Martínez, Pablo Velásquez, Luis Meseguer-Olmo, Piedad N. De Aza, Production and study of in vitro behaviour of monolithic α-tricalcium phosphate based ceramics in the system Ca3(PO4)2–Ca2SiO4 Ceramics International. ,vol. 37, pp. 2527- 2535 ,(2011) , 10.1016/J.CERAMINT.2011.03.062
Beatriz Paredes, Alfredo Santana, María I. Arribas, Néstor Vicente-Salar, Piedad N. de Aza, Enrique Roche, José Such, Juan A. Reig, Phenotypic differences during the osteogenic differentiation of single cell‐derived clones isolated from human lipoaspirates Journal of Tissue Engineering and Regenerative Medicine. ,vol. 5, pp. 589- 599 ,(2011) , 10.1002/TERM.351
S Serena, A Caballero, PN De Aza, MA Sainz, None, New evaluation of the in vitro response of silicocarnotite monophasic material Ceramics International. ,vol. 41, pp. 9411- 9419 ,(2015) , 10.1016/J.CERAMINT.2015.03.319
IM Martinez, PA Velasquez, PN De Aza, None, Synthesis and stability of α-tricalcium phosphate doped with dicalcium silicate in the system Ca3(PO4)2–Ca2SiO4 Materials Characterization. ,vol. 61, pp. 761- 767 ,(2010) , 10.1016/J.MATCHAR.2010.04.010
Isabel M. Martínez, Pablo Velásquez, Piedad N. Aza, The Sub‐System α‐TCPss‐Silicocarnotite Within the Binary System Ca3(PO4)2–Ca2SiO4 Journal of the American Ceramic Society. ,vol. 95, pp. 1112- 1117 ,(2011) , 10.1111/J.1551-2916.2011.05031.X
J. E. Stead, C. H. Ridsdale, LVII.—Crystals in basic converter slag J. Chem. Soc., Trans.. ,vol. 51, pp. 601- 610 ,(1887) , 10.1039/CT8875100601