Acetyleneiron tetracarbonyls: classical organometallic intermediates. synthesis and x-ray crystal structure of Fe2(CO)8(Ph2PC≡CBu-t)
作者： Arthur J. Carty , Wayne F. Smith , Nicholas J. Taylor
DOI: 10.1016/S0022-328X(00)91446-3
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摘要: Abstract The synthesis of Fe2(CO)8(Ph2PC≡CBu-t), a molecule containing Fe(CO)4(phosphine) and Fe(CO)4(acetylene) moieties is described. A single crystal X-ray structure analysis has provided for the first time, accurate molecular parameters classical intermediate type Fe(CO)4(acetylene).
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