ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION METALS I
作者： K. H. Pannell , G. M. Crawford
DOI: 10.1080/00958977308072984
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摘要: Abstract The reactions of bis-trimethylsilylacetylene and bis-trimethylsilylbutadiyne with various transition metal carbonyls have been studied. Both form stable complexes iron, cobalt manganese. infrared spectral data indicates that for the group IV substituted ligands pi-accepting ability increases in order C < Si Sn. Mass provides evidence existence novel bis-cyclobutadiene iron fragments also unknown tetra-silylcyclobutadiene.
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