Nanopatterning and bandgap grading to reduce defects in CdTe solar cells

作者: Jose L. Cruz-Campa , David Zubia , Xiaowang Zhou , Brandon A. Aguirre , Donald Ward

DOI: 10.1109/PVSC.2012.6317734

关键词:

摘要: We present simulation and experimental results proving the feasibility of a novel concept to increase efficiency CdTe based solar cells. In order achieve $0.50/W price in modules, higher efficiencies need be attained. The high defect density due lattice-mismatch between CdS reduces lifetime, voltage, propose use graded composition structure patterned substrate reduce defects, Innovative simulations using high-fidelity molecular dynamics predict that defect-free films are possible if film is with Zn constructed as nano-islands sizes below 90 nm. Both stresses. Also, creates back surface field an enhanced ohmic contact. have attempted grow ZnTe on substrates template micro nano-islands. Selective growths shown fewer grain boundaries when island size decreases 300 larger were obtained CdTe/ZnTe stack compared single layer CdTe. demonstrate for first time ability nanopatterned enhance uniformity thin

参考文章(14)
S.H. Demtsu, J.R. Sites, Quantification of losses in thin-film CdS/CdTe solar cells photovoltaic specialists conference. pp. 347- 350 ,(2005) , 10.1109/PVSC.2005.1488140
Z. C. Feng, H. C. Chou, A. Rohatgi, G. K. Lim, A. T. S. Wee, K. L. Tan, Correlations between CdTe/CdS/SnO2/glass solar cell performance and the interface/surface properties Journal of Applied Physics. ,vol. 79, pp. 2151- 2153 ,(1996) , 10.1063/1.361041
M CONTRERAS, J TUTTLE, A GABOR, A TENNANT, K RAMANATHAN, S ASHER, A FRANZ, J KEANE, L WANG, R NOUFI, High efficiency graded bandgap thin-film polycrystalline Cu(In,Ga) Se2-based solar cells Solar Energy Materials and Solar Cells. pp. 231- 246 ,(1996) , 10.1016/0927-0248(95)00145-X
A. Dhingra, A. Rothwarf, Computer simulation and modeling of graded bandgap CuInSe/sub 2//CdS based solar cells IEEE Transactions on Electron Devices. ,vol. 43, pp. 613- 621 ,(1996) , 10.1109/16.485544
J. J. Chavez, D. K. Ward, B. M. Wong, F. P. Doty, J. L. Cruz-Campa, G. N. Nielson, V. P. Gupta, D. Zubia, J. McClure, X. W. Zhou, Defect formation dynamics during CdTe overlayer growth Physical Review B. ,vol. 85, pp. 245316- ,(2012) , 10.1103/PHYSREVB.85.245316
K. Inoue, J.C. Harmand, T. Matsuno, High-quality InxGa1−xAs/InAlAs modulation-doped heterostructures grown lattice-mismatched on GaAs substrates Journal of Crystal Growth. ,vol. 111, pp. 313- 317 ,(1991) , 10.1016/0022-0248(91)90992-E
Stella A Quinones, Skanda M Ammu, Arev Escobedo, Mario Rodriguez, Jose Cruz-Campa, John McClure, David Zubia, None, SEM characterization of CdTe growth on CdTe(111) by close-spaced sublimation Journal of Materials Science: Materials in Electronics. ,vol. 18, pp. 1085- 1091 ,(2007) , 10.1007/S10854-007-9211-Y
Colin A. Wolden, Juanita Kurtin, Jason B. Baxter, Ingrid Repins, Sean E. Shaheen, John T. Torvik, Angus A. Rockett, Vasilis M. Fthenakis, Eray S. Aydil, Photovoltaic manufacturing: Present status, future prospects, and research needs Journal of Vacuum Science and Technology. ,vol. 29, pp. 030801- ,(2011) , 10.1116/1.3569757