Synthesis and characterization of cationic cyclopalladated complexes derived from p - tert -butyl-calix[4]arene bisphosphite with nitrogen donors
作者： Pathik Maji
DOI: 10.1016/J.ICA.2011.01.085
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摘要: Abstract A series of new cationic cyclopalladated complexes 2–6 have been synthesized from neutral complex 1 p-tert-butyl-calix[4]arene bisphosphite with various nitrogen donor ligands (acetonitrile, pyridine, aniline, (R)-(+)-1-phenylethylamine and 4,4′-bipyridine) in presence Ag(OSO2CF3) as a chloride scavenger. These characterized by NMR spectroscopy. Single crystal X-ray diffraction studies performed on 3 6 solid state reveal nearly square planar geometry around the metal distorted cone conformation calix[4]arene framework. based hetero having variable steric electronic properties could be efficient catalysts for important organic transformation reactions.
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sci-hub.se 参考文章(27)
Luigi Mandolini, Rocco Ungaro, Calixarenes in action Imperial College Press. ,(2000) , 10.1142/P168
Arindam Sarkar, Munirathinam Nethaji, Setharampattu S. Krishnamurthy, Structure and solution dynamics of a P-N-P ligand attached to calix[4]arene scaffold and its palladium dichloride complex Polyhedron. ,vol. 26, pp. 3904- 3910 ,(2007) , 10.1016/J.POLY.2007.04.019
Cyrille Loeber, Dominique Matt, André De Cian, Jean Fischer, Multifunctional phosphane and phosphane oxide ligands derived from p-tert-butylcalix[4]arene. Synthesis of a large diphosphane with C2 symmetry and behaving as a cis or trans binding ligand Journal of Organometallic Chemistry. ,vol. 475, pp. 297- 305 ,(1994) , 10.1016/0022-328X(94)84035-0
Oleg Aleksiuk, Flavio Grynszpan, Silvio E. Biali, Preparation, Structure and Stereodynamics of Phosphorus-Bridged Calixarenes Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 19, pp. 237- 256 ,(1994) , 10.1007/BF00708985
Arindam Sarkar, Setharampattu S. Krishnamurthy, Munirathinam Nethaji, Calix[4]arene bisphosphite ligands bearing two distal 2,2′-biphenyldioxy or 2,2′-binaphthyldioxy moieties: conformational flexibility and allyl–palladium complexes Tetrahedron. ,vol. 65, pp. 374- 382 ,(2009) , 10.1016/J.TET.2008.10.031
Cedric Dieleman, Cyrille Loeber, Dominique Matt, Andr� De Cian, Jean Fischer, Facile synthetic route to cone-shaped phosphorylated [CH2P(O)Ph2] calix[4]arenes Journal of The Chemical Society-dalton Transactions. pp. 3097- 3100 ,(1995) , 10.1039/DT9950003097
Arindam Sarkar, Munirathinam Nethaji, Setharampattu S. Krishnamurthy, Phosphite ligands derived from distally and proximally substituted dipropyloxy calix[4]arenes and their palladium complexes: Solution dynamics, solid-state structures and catalysis Journal of Organometallic Chemistry. ,vol. 693, pp. 2097- 2110 ,(2008) , 10.1016/J.JORGANCHEM.2008.03.008
Catherine Wieser, Cedric B. Dieleman, Dominique Matt, Calixarene and resorcinarene ligands in transition metal chemistry Coordination Chemistry Reviews. ,vol. 165, pp. 93- 161 ,(1997) , 10.1016/S0010-8545(97)90153-3
Matthias Stolmàr, Carlo Floriani, Angiola Chiesi-Villa, Corrado Rizzoli, p-tert-Butylcalix[4]arene Tetrakis(diphenylphosphinite) and Tetrakis(dimethylphosphinite) Acting as Phosphorus Binding Surfaces for Monometallic and Homo- and Heterodimetallic Fragments. Inorganic Chemistry. ,vol. 36, pp. 1694- 1701 ,(1997) , 10.1021/IC9615382
Seiji Shinkai, Calixarenes - the third generation of supramolecules Tetrahedron. ,vol. 49, pp. 8933- 8968 ,(1993) , 10.1016/S0040-4020(01)91215-3