Facile synthetic route to cone-shaped phosphorylated [CH2P(O)Ph2] calix[4]arenes
作者： Cedric Dieleman , Cyrille Loeber , Dominique Matt , Andr� De Cian , Jean Fischer
DOI: 10.1039/DT9950003097
关键词:
摘要: Selective incorporation of one, two or four CH2P(O)Ph2 substituents at specific sites in para-tert-butylcalix[4] arene was achieved using NaH and an appropriate alkylating agent; the tetrasubstituted compound (structure established by X-ray crystallography) quantitatively reduced to corresponding tetraphosphine L6 which, reaction with [{Pd(C6H4CH2NMe2-o)Cl}2], gave access tetranuclear complex [{Pd(C6H4CH2NMe2-o)Cl}4L6].
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sci-hub.se 参考文章(13)
Bing Xu, Timothy M. Swager, Rigid bowlic liquid crystals based on tungsten-oxo calix[4]arenes: host-guest effects and head-to-tail organization Journal of the American Chemical Society. ,vol. 115, pp. 1159- 1160 ,(1993) , 10.1021/JA00056A056
Cyrille Loeber, Dominique Matt, André De Cian, Jean Fischer, Multifunctional phosphane and phosphane oxide ligands derived from p-tert-butylcalix[4]arene. Synthesis of a large diphosphane with C2 symmetry and behaving as a cis or trans binding ligand Journal of Organometallic Chemistry. ,vol. 475, pp. 297- 305 ,(1994) , 10.1016/0022-328X(94)84035-0
Seiji Shinkai, Calixarenes - the third generation of supramolecules Tetrahedron. ,vol. 49, pp. 8933- 8968 ,(1993) , 10.1016/S0040-4020(01)91215-3
Alessandro Casnati, Andrea Pochini, Rocco Ungaro, Franco Ugozzoli, Francoise Arnaud, Stefano Fanni, Marie-Jose Schwing, Richard J. M. Egberink, Feike de Jong, David N. Reinhoudt, Synthesis, Complexation, and Membrane Transport Studies of 1,3-Alternate Calix[4]arene-crown-6 Conformers: A New Class of Cesium Selective Ionophores Journal of the American Chemical Society. ,vol. 117, pp. 2767- 2777 ,(1995) , 10.1021/JA00115A012
Koji Iwamoto, Koji Araki, Seiji Shinkai, Syntheses of all possible conformational isomers of O-alkyl-p-t-butylcalix[4]arenes Tetrahedron. ,vol. 47, pp. 4325- 4342 ,(1991) , 10.1016/S0040-4020(01)87102-7
Ion Neda, Hans-J. Plinta, Ralf Sonnenburg, Axel Fischer, Peter G. Jones, Reinhard Schmutzler, DARSTELLUNG VON PHOSPHOR- UND FLUORHALTIGEN CALIX 4 AREN-DERIVATEN. KONFORMATIONSANALYSE, TRENNUNG DER KONFORMERE UND RONTGENSTRUKTURANALYSE AN EINEM KONUSKONFORMER Chemische Berichte. ,vol. 128, pp. 267- 273 ,(1995) , 10.1002/CBER.19951280310
Arturo Arduini, Stefano Fanni, Giuseppe Manfredi, Andrea Pochini, Rocco Ungaro, Anna R. Sicuri, Franco Ugozzoli, Direct Regioselective Formylation of Tetraalkoxycalix[4]arenes Fixed in the Cone Conformation and Synthesis of New Cavitands Journal of Organic Chemistry. ,vol. 60, pp. 1448- 1453 ,(1995) , 10.1021/JO00110A054
Rocco Ungaro, Alessandro Casnati, Franco Ugozzoli, Andrea Pochini, Jean-François Dozol, Clement Hill, Hélène Rouquette, 1,3‐Dialkoxycalix[4]arenecrowns‐6 in 1,3‐Alternate Conformation: Cesium‐Selective Ligands that Exploit Cation‐Arene Interactions Angewandte Chemie. ,vol. 33, pp. 1506- 1509 ,(1994) , 10.1002/ANIE.199415061
Volker Böhmer, Calixarenes, Macrocycles with(Almost) Unlimited Possibilities Angewandte Chemie International Edition in English. ,vol. 34, pp. 713- 745 ,(1995) , 10.1002/ANIE.199507131
Hein K. A. C. Coolen, Piet W. N. M. van Leeuwen, Roeland J. M. Nolte, A RhI-Centered Cage Compound with Selective Catalytic Properties Angewandte Chemie International Edition in English. ,vol. 31, pp. 905- 907 ,(1992) , 10.1002/ANIE.199209051