Noncovalent interaction of carbon nanostructures.

摘要: ConspectusThe potential application of carbon nanomaterials in biology and medicine increases the necessity to understand nature their interactions with living organisms environment. The primary forces interaction at nano–bio interface are mostly noncovalent nature. Quantifying such identifying various factors that influence is a question outstanding fundamental interest academia industry.In this Account, we have summarized our recent studies understanding nanostructures (CNSs), which were obtained by employing first-principles calculations on model systems representing nanotubes (CNTs) graphene. Bestowed an extended sp2 network, common feature all these nanostructures, they exhibit π–π aromatic molecules (benzene, naphthalene, nucleobases, amino acids), cation−π type metal ions, anion−π anio...