The Dimeric “Hand-Shake” Motif in Complexes and Metallo-Supramolecular Assemblies of Cyclotriveratrylene-Based Ligands
作者： Christopher Carruthers , Tanya K. Ronson , Christopher J. Sumby , Aleema Westcott , Lindsay P. Harding
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摘要: A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which ligand arm one is the intra-cavity guest another vice versa. This "hand-shake" found trinuclear transition complex [Cu(3)Cl(6)(1)]CH(3)CN1.5 H(2)O 1 tris(4-[2,2',6',2''-terpyridyl]benzyl)cyclotriguaiacylene; self-included M(4)L(4) tetrahedral metallo-supramolecular assembly [Ag(4)(2)(4)] (BF(4))(4) 2 tris-(2-quinolylmethyl)cyclotriguaiacylene; 1D coordination chains [Ag(4)]ReO(4) CH(3)CN [Ag(5)]SbF(6)3 DMFH(2)O 4 tris(1H-imidazol-1-yl)cyclotriguaiacylene 5 tris{4-(2-pyridyl)benzyl}cyclotriguaiacylene; acetone tris{4-(2-pyridyl)benzyl-amino}cyclotriguaiacylene. Clathrates do not same motif, although has an extended that gives hexagonal network.
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sci-hub.se 参考文章(64)
B. T. Ibragimov, K. K. Makhkamov, K. M. Beketov, Polymorphism of Crystalline Inclusion Complexes and Unsolvated Hosts. Part 8 Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 35, pp. 583- 593 ,(1999) , 10.1023/A:1008000713645
Mohamed Makha, Michaele J. Hardie, Colin L. Raston, Inter-digitation approach to encapsulation of C60: [C60⊂ (p-phenylcalix[5]arene)2] Chemical Communications. ,vol. 2002, pp. 1446- 1447 ,(2002) , 10.1039/B203688F
Markus Albrecht, Ingo Janser, Sebastian Meyer, Patrick Weis, Roland Fröhlich, A metallosupramolecular tetrahedron with a huge internal cavity. Chemical Communications. pp. 2854- 2855 ,(2003) , 10.1039/B309495B
J. F. Gallagher, G. Ferguson, V. Böhmer, D. Kraft, Self inclusion in a calix[5]arene structure; structure of the cone conformer of a pentahydroxy‐p‐tert‐butylcalix[5]arene Acta Crystallographica Section C-crystal Structure Communications. ,vol. 50, pp. 73- 77 ,(1994) , 10.1107/S0108270193007152
Eric B. Brouwer, Kostantin A. Udachin, Gary D. Enright, John A. Ripmeester, Kristopher J. Ooms, Peter A. Halchuk, Self-inclusion and paraffin intercalation of the p-tert-butylcalix[4]arene host: a neutral organic clay mimic Chemical Communications. pp. 565- 566 ,(2001) , 10.1039/B009133M
Delphine Felder, Benoît Heinrich, Daniel Guillon, Jean-François Nicoud, Jean-François Nierengarten, A liquid crystalline supramolecular complex of C60 with a cyclotriveratrylene derivative Chemistry: A European Journal. ,vol. 6, pp. 3501- 3507 ,(2000) , 10.1002/1521-3765(20001002)6:19<3501::AID-CHEM3501>3.0.CO;2-0
Christopher J. Sumby, Michael J. Carr, Andreas Franken, John D. Kennedy, Colin A. Kilner, Michaele J. Hardie, Crystal-packing motifs of [Ag4L4]4+ star-burst tetrahedra New Journal of Chemistry. ,vol. 30, pp. 1390- 1396 ,(2006) , 10.1039/B609356F
Leonard J Barbour, X-Seed — A Software Tool for Supramolecular Crystallography Journal of Supramolecular Chemistry. ,vol. 1, pp. 189- 191 ,(2001) , 10.1016/S1472-7862(02)00030-8
David Bardelang, Laurence Charles, Jean-Pierre Finet, Laszlo Jicsinszky, Hakim Karoui, Sylvain R. A. Marque, Valérie Monnier, Antal Rockenbauer, Roseline Rosas, Paul Tordo, α-Phenyl-N-tert-butylnitrone-type derivatives bound to β-cyclodextrins: Syntheses, thermokinetics of self-inclusion and application to superoxide spin-trapping Chemistry: A European Journal. ,vol. 13, pp. 9344- 9354 ,(2007) , 10.1002/CHEM.200700369
André Collet, Cyclotriveratrylenes and cryptophanes Tetrahedron. ,vol. 43, pp. 5725- 5759 ,(1987) , 10.1016/S0040-4020(01)87780-2