Self-inclusion and paraffin intercalation of the p-tert-butylcalix[4]arene host: a neutral organic clay mimic
作者： Eric B. Brouwer , Kostantin A. Udachin , Gary D. Enright , John A. Ripmeester , Kristopher J. Ooms
DOI: 10.1039/B009133M
关键词: Tetradecane 、 Crystallography 、 Host (biology) 、 Molecule 、 Crystallization 、 Inclusion (mineral) 、 Intercalation (chemistry) 、 Chemistry 、 Lamellar structure 、 Organic chemistry
摘要: Two newly identified structures arise upon the crystallisation of p-tert-butylcalix[4]arene host molecule from tetradecane: guest-free, self-included structure, and a 1:1 host–guest structure in which paraffin guest is anchored bowl-shaped cavity intercalates layers of molecules lamellar reminiscent clays.
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