Ladderphanes: a new type of duplex polymers.

作者: Tien-Yau Luh

DOI: 10.1021/AR300170B

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摘要: A polymeric ladderphane is a step-like structure comprising multiple layers of linkers covalently connected to two or more backbones. The can be planar aromatic, macrocyclic metal complexes, three-dimensional organic organometallic moieties. Structurally, DNA molecule special kind ladderphane, where the cofacially aligned base-pair pendants are linked through hydrogen bonding. greater understanding this class molecules could help researchers develop new synthetic capable similar transfer chemical information.In Account, we summarize our studies strategy, design, synthesis, characterization, replications, and photophysical properties, assembly range double-stranded ladderphanes with many fascinating structures. We employed norbornene moieties fused N-arylpyrrolidine connect relatively rigid linkers. Ring opening metathesis polymerizations (ROMP) these bis-norbornenes using ...

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