Synthesis of polyaniline/camphor sulfonic acid in formic acid medium and their blends with polyamide-6 by in situ polymerization

作者: Anderson RA Schettini , Rosa CD Peres , Bluma G Soares , None

DOI: 10.1016/J.SYNTHMET.2009.04.006

关键词:

摘要: Blends of polyaniline doped with camphor sulfonic acid (PAni.CSA) and polyamide 6 (PA6) were prepared for the first time by in situ polymerization aniline presence a solution PA6 formic acid. The conductivity values blends both cast are range useful electrostatic charge dissipation materials. blend containing 10% PAni.CSA was higher, when process used, indicating formation conducting pathways higher extension. Most presented only one irreversible peak cyclic voltammetry, which is attributed to defects along chains. These may be caused as solvent, observed Fourier transformer infrared spectroscopy pure

参考文章(19)
Ayşegül Gök, Beki̇r Sari, None, Chemical synthesis and characterization of some conducting polyaniline derivatives: Investigation of the effect of protonation medium Journal of Applied Polymer Science. ,vol. 84, pp. 1993- 2000 ,(2002) , 10.1002/APP.10487
C.-H. Hsu, H. Shih, S. Subramoney, A.J. Epstein, High tenacity, high modulus conducting polyaniline composite fibers Synthetic Metals. ,vol. 101, pp. 677- 680 ,(1999) , 10.1016/S0379-6779(98)00340-3
ET Kang, KG Neoh, KL Tan, POLYANILINE: A POLYMER WITH MANY INTERESTING INTRINSIC REDOX STATES Progress in Polymer Science. ,vol. 23, pp. 277- 324 ,(1998) , 10.1016/S0079-6700(97)00030-0
Ananya Dan, P. K. Sengupta, Synthesis and characterization of polyaniline prepared in formic acid medium Journal of Applied Polymer Science. ,vol. 91, pp. 991- 999 ,(2004) , 10.1002/APP.13204
H. K. Chaudhari, D. S. Kelkar, X-ray diffraction study of doped polyaniline Journal of Applied Polymer Science. ,vol. 62, pp. 15- 18 ,(1996) , 10.1002/(SICI)1097-4628(19961003)62:1<15::AID-APP3>3.0.CO;2-V
A.G. Bedekar, S.F. Patil, R.C. Patil, K. Vijayamohanan, Effect of monomer concentration and substrate resistance on redox behaviour of polyaniline films Materials Chemistry and Physics. ,vol. 48, pp. 76- 81 ,(1997) , 10.1016/S0254-0584(97)80082-X
Daniel Abraham, A. Bharathi, S.V. Subramanyam, Highly Conducting Polymer Blend Films of Polyaniline and Nylon 6 by Cosolvation in an Organic Acid Polymer. ,vol. 37, pp. 5295- 5299 ,(1996) , 10.1016/0032-3861(96)00419-3
Q.-H. Zhang, Z.-C. Sun, J. Li, X.-H. Wang, H.-F. Jin, X.-B. Jing, F.-S. Wang, Conductive polyaniline / poly-ω-aminoundecanoyle blending fiber Synthetic Metals. ,vol. 102, pp. 1198- 1199 ,(1999) , 10.1016/S0379-6779(98)01106-0