Effect of metal-sulfide additives on charge/discharge reactions of the alkaline iron electrode

作者: T.S. Balasubramanian , A.K. Shukla

DOI: 10.1016/0378-7753(93)85008-C

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摘要: Abstract The effect of FeS, PbS and Bi2S3 additives on the charge/discharge reactions porous iron electrodes in alkaline media are examined by means steady-state galvanostatic potentiostatic polarization, as well gasometric methods. It is found that these do not affect reaction kinetics fully-charged electrodes, but retard rapid onset passivation. By contrast, a distinct observed hydrogen-evolution during electrode charging.

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