Pulsed-laser induced chain addition reaction of pentanal to diethyl maleate
作者： R Stringat , G Fabre , R Fellous , P Paquet
DOI: 10.1016/S0040-4039(00)74245-6
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摘要: A pentanal and diethyl maleate mixture (concentration ratio 51) is irradiated with a frequency tripled Nd-YAG laser (355 nm) in the peak interval 1.5KW.cm−2 – 8.75MW.cm−2. Diethyl pentanoyl succinate formed selectivity by chain addition reaction an intensity dependant quantum yield which can reach 2000%.
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