Controlling the Cross-Linking Density of Supramolecular Hydrogels Formed by Heterotelechelic Associating Copolymers

摘要: Associating polymers constitute a fascinating class of materials because the richness in their rheological behaviors. They may find application numerous areas, provided that mechanical properties can be tailored to fulfill specific requirements. In this context, study aims control magnitude viscoelastic response coordination micellar hydrogels built through hierarchical assembly heterotelechelic poly(N-isopropylacrylamide). The influence different variables on those is investigated and discussed term cross-linking density. respect, two distinct regimes are distinguished correspond well percolated network, with high density, weakly low