Direct observation of phase transition of GeSbTe thin films by Atomic Force Microscope

作者: Fei Yang , Ling Xu , Rui Zhang , Lei Geng , Liang Tong

DOI: 10.1016/J.APSUSC.2012.06.025

关键词:

摘要: Abstract GeSbTe (GST) thin films were deposited on quartz substrates using electron beam evaporation system and then annealed in nitrogen atmosphere at different temperatures, ranging from 20 °C to 300 °C. X-ray diffraction (XRD) Atomic Force microscope (AFM) measurements used characterize the as-deposited post-annealed films. Annealing treatment was found induce changes microstructure, surface roughness grain size, indicating that with increase of annealing temperature, amorphous GST first changed face-centered-cubic (fcc) phase stable hexagonal (hex) phase. Meanwhile, conductive-AFM (C-AFM) produce crystallized dots I–V spectroscopy results show can switch state crystalline threshold voltage. After switching, curve exhibits ohmic characteristic, which is usually observed By applying repeated spectroscopies films, nuclei observed. As times increases, area written center mark begin ablate. The AFM images shape marks an ablated a raised ring surrounding it.

参考文章(13)
E. Rimini, R. De Bastiani, E. Carria, M. G. Grimaldi, G. Nicotra, C. Bongiorno, C. Spinella, Crystallization of sputtered-deposited and ion implanted amorphous Ge2Sb2Te5 thin films Journal of Applied Physics. ,vol. 105, pp. 123502- ,(2009) , 10.1063/1.3148288
Bong-Sub Lee, John R. Abelson, Stephen G. Bishop, Dae-Hwan Kang, Byung-ki Cheong, Ki-Bum Kim, Investigation of the optical and electronic properties of Ge2Sb2Te5 phase change material in its amorphous, cubic, and hexagonal phases Journal of Applied Physics. ,vol. 97, pp. 093509- ,(2005) , 10.1063/1.1884248
Kentaro Sugawara, Tamihiro Gotoh, Keiji Tanaka, Scanning tunneling microscope modifications of amorphous Ge–Sb–Te films Journal of Non-crystalline Solids. pp. 37- 41 ,(2003) , 10.1016/S0022-3093(03)00373-9
Jin Zhu, Feng Xu, Seunghun Hong, Chad A. Mirkin, Richard D. Piner, "Dip-Pen" Nanolithography Science. ,vol. 283, pp. 661- 663 ,(1999) , 10.1126/SCIENCE.283.5402.661
JunHo Kim, Myeung Hoi Kwon, Ki-Bong Song, Characterization of nanoscale recording mark on Ge2Sb2Te5 film Ultramicroscopy. ,vol. 108, pp. 1246- 1250 ,(2008) , 10.1016/J.ULTRAMIC.2008.04.080
S. Gidon, O. Lemonnier, B. Rolland, O. Bichet, C. Dressler, Y. Samson, Electrical probe storage using Joule heating in phase change media Applied Physics Letters. ,vol. 85, pp. 6392- 6394 ,(2004) , 10.1063/1.1834718
Tamihiro Gotoh, Kentaro Sugawara, Keiji Tanaka, Nanoscale electrical phase-change in GeSb2Te4 films with scanning probe microscopes Journal of Non-crystalline Solids. ,vol. 299302, pp. 968- 972 ,(2002) , 10.1016/S0022-3093(01)01061-4
Stanford R. Ovshinsky, Reversible Electrical Switching Phenomena in Disordered Structures Physical Review Letters. ,vol. 21, pp. 1450- 1453 ,(1968) , 10.1103/PHYSREVLETT.21.1450
Noboru Yamada, Eiji Ohno, Kenichi Nishiuchi, Nobuo Akahira, Masatoshi Takao, Rapid‐phase transitions of GeTe‐Sb2Te3 pseudobinary amorphous thin films for an optical disk memory Journal of Applied Physics. ,vol. 69, pp. 2849- 2856 ,(1991) , 10.1063/1.348620