Metal Catalyzed Oxidations of Unsaturated Hydrocarbons by Molecular Oxygen. The Use of Multi-Step Catalysis
作者： J.-E. Bäckvall
DOI: 10.1016/S0167-2991(09)60804-1
关键词:
摘要: Abstract Selective 1,4-oxidations of conjugated dienes were developed. Many these 1,4-oxidized are important synthetic intermediates. Multi-step catalysis using the catalytic system Pd(II)-hydroquinone was By a “triple catalytic” consisting macrocyclic metal complex, hydroquinone, and palladium acetate, mild selective oxidation 1,3-dienes olefins by molecular oxygen
sci-hub.se 参考文章(25)
J.E. Bäckvall, S.E. Byström, Nyström J.E., Stereocontrolled synthesis of (R*R*)- and (R*S*)-5-hydroxy-2-methylhexanoic acid lactones : Pheromone of the carpenter bee via palladium-catalyzed reactions Tetrahedron. ,vol. 41, pp. 5761- 5764 ,(1985) , 10.1016/S0040-4020(01)91414-0
Tamio Hayashi, Keiji Kabeta, Tsunehiro Yamamoto, Kohei Tamao, Makoto Kumada, Optically active cyclic allylsilanes: Preparation by asymmetric hydrosilylation and anti stereochemistry in SE' reactions☆ Tetrahedron Letters. ,vol. 24, pp. 5661- 5664 ,(1983) , 10.1016/S0040-4039(00)94167-4
Jan E. Baeckvall, Jan E. Nystroem, Ruth E. Nordberg, Stereo- and regioselective palladium-catalyzed 1,4-acetoxychlorination of 1,3-dienes. 1-Acetoxy-4-chloro-2-alkenes as versatile synthons in organic transformations Journal of the American Chemical Society. ,vol. 107, pp. 3676- 3686 ,(1985) , 10.1021/JA00298A043
Jan E. Baeckvall, Styrbjoern E. Bystroem, Ruth E. Nordberg, Stereo- and regioselective palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes Journal of Organic Chemistry. ,vol. 49, pp. 4619- 4631 ,(1984) , 10.1021/JO00198A010
Jiro Tsuji, Isao Shimizu, Keiji Yamamoto, Convenient general synthetic method for 1,4- and 1,5-diketones by palladium catalyzed oxidation of α-allyl and α-3-butenyl ketones Tetrahedron Letters. ,vol. 17, pp. 2975- 2976 ,(1976) , 10.1016/S0040-4039(01)85504-0
Heinz Stangl, Reinhard Jira, Die durch palladium(II)chlorid und kupfer(II)chlorid katalysierte oxychlorierung von äthylen zu äthylenchlorhydrin Tetrahedron Letters. ,vol. 11, pp. 3589- 3592 ,(1970) , 10.1016/S0040-4039(01)98535-1
Joseph M. O'Connor, Barbara J. Stallman, W. Gregg Clark, Arthur Y. L. Shu, Ralph E. Spada, Thomas M. Stevenson, Harold A. Dieck, Some aspects of palladium-catalyzed reactions of aryl and vinylic halides with conjugated dienes in the presence of mild nucleophiles Journal of Organic Chemistry. ,vol. 14, pp. 807- 809 ,(1983) , 10.1021/JO00154A010
Ove S. Andell, Jan-E. Bäckvall, Christina Moberg, Klaus D. Krautwurst, Povl Krogsgaard-Larsen, Ragnar Ryhage, Roland Isaksson, Nickel- and palladium-catalyzed additions of nucleophiles to cyclic 1,3-dienes Acta Chemica Scandinavica. ,vol. 17, pp. 184- 189 ,(1986) , 10.3891/ACTA.CHEM.SCAND.40B-0184
Jiro Tsuji, Makoto Minato, Oxidation of olefins to ketones in combination with electrooxidation Tetrahedron Letters. ,vol. 28, pp. 3683- 3686 ,(1987) , 10.1016/S0040-4039(00)96354-8
Jan E. Baeckvall, Palladium in some selective oxidation reactions Accounts of Chemical Research. ,vol. 15, pp. 335- 342 ,(1983) , 10.1021/AR00093A004