Optically active cyclic allylsilanes: Preparation by asymmetric hydrosilylation and anti stereochemistry in SE' reactions☆
作者： Tamio Hayashi , Keiji Kabeta , Tsunehiro Yamamoto , Kohei Tamao , Makoto Kumada
DOI: 10.1016/S0040-4039(00)94167-4
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摘要: Abstract Reaction of optically active cyclic allylsilanes, ( S )-3-(trimethylsilyl)cyclopentene and -cyclohexene, which are prepared by palladium-catalyzed asymmetric hydrosilylation dienes, with ethylene oxide in the presence titanium chloride proceeded anti stereochemistry to give R )-3-(2-hydroxyethyl)cyclopentene respectively.
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