Process for making methylphosphonic dichloride

作者: John A. Wojtowicz

DOI:

关键词:

摘要: Disclosed is a process for producing methylphosphonic dichloride comprising reacting dimethyl methylphosphonate with chlorinating agent selected from the group consisting of thionyl chloride and phosgene in presence catalytic amount an inorganic halide ammonium metallic halides where metal cation metals Groups IA, IIA, IIIB, IVB, VB, VIB, VIIB, VIIIB, IB, IIB IIIA Periodic Table.

参考文章(9)
Manfred Finke, Klaus Dehmer, Gerhard Stahler, Hans-Jerg Kleiner, Process for the preparation of phosphonic acid dihalides ,(1973)
Kurt Moedritzer, R. E. Miller, A Convenient One-Step, High-Yield Preparation of Methylphosphonyl Dichloride from Dimethyl Methylphosphonate Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. ,vol. 4, pp. 417- 427 ,(1974) , 10.1080/00945717408069671
Donald H Briggeman, Longacre Alan, Jr Charles J Smith, Production of methyl dichlorophosphine oxide ,(1954)
William P. Enlow, Ingenuin Hechenbleikner, Oxidation of alkyl phosphonous dichlorides ,(1982)
Jack W Armstrong, Thomas P Dawson, Method of manufacture of rp(o) cl2 from rp(o)(or)2 and socl2 ,(1955)