A truce on the Smiles rearrangement: revisiting an old reaction--the Truce-Smiles rearrangement.
作者： Timothy J. Snape
DOI: 10.1039/B808960D
关键词:
摘要: The Smiles rearrangement is the intramolecular nucleophilic aromatic substitution reaction incorporating a heteroatom as component and an activated electrophilic arene. One particular variation—the Truce–Smiles rearrangement—utilises carbon-based nucleophile arene which does not require additional activation. Such variation generates new carbon–carbon bond synthetic utility of this relatively under-utilised discussed in tutorial review.
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