Physicochemical Properties of an Hydrophobic Ionic Liquid (Aliquat 336) in a Polar Protic Solvent (Formamide) at Different Temperatures
作者： Yousra Litaiem , Mahmoud Dhahbi
DOI: 10.1080/01932691.2013.862170
关键词:
摘要: The physicochemical and transport proprieties have been determined for binary mixtures Aliquat 336/Formamide in the temperature range of 298.15 to 313.15 K. variation tendency viscosity/conductivity with composition was explained through disruption molecular solutes ionic association or aggregation liquids (ILs). semiempirical equation proposed by Jones Dole used describe viscosity salt concentration (C). In IL-rich region, molar conductivity follows cube root law, which predicted quasi-lattice model introduced Gosh. two processes were well described Arrhenius law. From this, activation energies (E a,η) a,Λ) are then deduced. Molecular interactions structures discussed from excess volumes V E.
sci-hub.se 参考文章(37)
Mahendra Nath Roy, Arijit Bhattacharjee, Palash Chakraborti, Investigation on molecular interactions of nicotinamide in aqueous citric acid monohydrate solutions with reference to manifestation of partial molar volume and viscosity B-coefficient measurements Thermochimica Acta. ,vol. 507, pp. 135- 141 ,(2010) , 10.1016/J.TCA.2010.05.014
D. J. P. Out, J. M. Los, Viscosity of aqueous solutions of univalent electrolytes from 5 to 95°C Journal of Solution Chemistry. ,vol. 9, pp. 19- 35 ,(1980) , 10.1007/BF00650134
Haiyan Gao, Feng Qi, Haijun Wang, Densities and volumetric properties of binary mixtures of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate with benzaldehyde at T=(298.15 to 313.15)K The Journal of Chemical Thermodynamics. ,vol. 41, pp. 888- 892 ,(2009) , 10.1016/J.JCT.2009.02.007
Paloma Navia, Jacobo Troncoso, Luis Romaní, Viscosities for Ionic Liquid Binary Mixtures with a Common Ion Journal of Solution Chemistry. ,vol. 37, pp. 677- 688 ,(2008) , 10.1007/S10953-008-9260-8
Michał Zapałowski, Witold M Bartczak, Structural and dynamical properties of concentrated aqueous NaOH solutions: a computer simulation study Computational Biology and Chemistry. ,vol. 24, pp. 459- 468 ,(2000) , 10.1016/S0097-8485(99)00084-4
Ramzi Zarrougui, Mahmoud Dhahbi, Daniel Lemordant, Effect of Temperature and Composition on the Transport and Thermodynamic Properties of Binary Mixtures of Ionic Liquid N-Butyl-N-methylpyrrolidinium bis(Trifluoromethanesulfonyl)imide and Propylene Carbonate Journal of Solution Chemistry. ,vol. 39, pp. 921- 942 ,(2010) , 10.1007/S10953-010-9562-5
Anil Kumar Nain, Densities and volumetric properties of (acetonitrile + an amide) binary mixtures at temperatures between 293.15 K and 318.15 K The Journal of Chemical Thermodynamics. ,vol. 38, pp. 1362- 1370 ,(2006) , 10.1016/J.JCT.2006.01.015
YingJie Xu, Yan Gao, LiQun Zhang, Jia Yao, CongMin Wang, HaoRan Li, Microscopic structures of ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate in water probed by the relative chemical shift Science China Chemistry. ,vol. 53, pp. 1561- 1565 ,(2010) , 10.1007/S11426-010-3198-6
K. V. Schubert, G. Busse, R. Strey, M. Kahlweit, Microemulsions with formamide as polar solvent The Journal of Physical Chemistry. ,vol. 97, pp. 248- 254 ,(1993) , 10.1021/J100103A043
L.A.S. Ries, F.A. do Amaral, K. Matos, E.M.A. Martini, M.O. de Souza, R.F. de Souza, Evidence of change in the molecular organization of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid solutions with the addition of water Polyhedron. ,vol. 27, pp. 3287- 3293 ,(2008) , 10.1016/J.POLY.2008.07.029