作者: Samir M. El-Medani , Shahera M. Shohayeb , Mohamed M. Shoukry
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摘要: Complex formation equillibria of [Pd(DAP)(H2O)2]2+ (DAP = 1,3-diaminopropane) with Cl−, OH−, cyclobutane dicarboxylic acid (CBDCA), amino acids, peptides and DNA unit constituents have been investigated. Stoichiometries stability constants the complexes were determined at 37°C 0.16 M NaNO3 ionic strength. The results showed 1:1 acids CBDCA. Peptides form both corresponding deprotonated amide species. 1:2 complexes. [Pd(DAP)(CBDCA)] was isolated characterized. concentration distribution in solution evaluated.