Al-Si-N thin films deposited by laser ablation: Effect of plasma parameters on mechanical and optical properties

作者: L.P. Rivera , Enrique Camps , Stephen Muhl , Rafael Basurto , A. Zeinert

DOI: 10.1016/J.MATERRESBULL.2017.10.044

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摘要: Abstract Al-Si-N thin films were deposited using simultaneous laser ablation of silicon and aluminum targets in a nitrogen atmosphere at substrate temperature 200 °C. The content the was studied as function plasma parameters (mean ion kinetic energy density), produced by target. measured means planar Langmuir probe optical emission spectroscopy. chemical composition determined X-ray photoelectron results showed dependence between density. Optical spectroscopy measurements that variations working pressure changes intensity excited species (N 2 + , Si 2+ Al 0 ), incorporation these elements into films. For 0.6 Pa, hardness gave maximum 30 ± 1.5 GPa for 4 at.%. constants (refractive index extinction coefficient) direct band gap evaluated

参考文章(50)
Lu׳an Guo, Guangde Chen, Youzhang Zhu, Xiangyang Duan, Honggang Ye, The growth of Sea-urchin-like AlN nanostructures by modified CVD and their Field Emission properties Journal of Crystal Growth. ,vol. 426, pp. 49- 53 ,(2015) , 10.1016/J.JCRYSGRO.2015.05.008
Eleonora Santecchia, A.M.S. Hamouda, Farayi Musharavati, Erfan Zalnezhad, Marcello Cabibbo, Stefano Spigarelli, Wear resistance investigation of titanium nitride-based coatings Ceramics International. ,vol. 41, pp. 10349- 10379 ,(2015) , 10.1016/J.CERAMINT.2015.04.152
A. R. Striganov, N. S. Sventitskii, Tables of spectral lines of neutral and ionized atoms Springer US. ,(1968) , 10.1007/978-1-4757-6610-3
Claude Phipps, None, Laser Ablation and its Applications Laser Ablation and its Applications. ,vol. 129, ,(2007) , 10.1007/978-0-387-30453-3
Ga-er Yu, Mohan J. Edirisinghe, Dudley S. Finch, Brian Ralph, John Parrick, Synthesis of α-silicon nitride powder from a polymeric precursor Journal of The European Ceramic Society. ,vol. 15, pp. 581- 590 ,(1995) , 10.1016/0955-2219(95)00011-I
Aude Pélisson-Schecker, Hans Josef Hug, Jörg Patscheider, Morphology, microstructure evolution and optical properties of Al–Si–N nanocomposite coatings Surface & Coatings Technology. ,vol. 257, pp. 114- 120 ,(2014) , 10.1016/J.SURFCOAT.2014.08.053
N C M Fuller, M V Malyshev, V M Donnelly, Irving P Herman, Characterization of transformer coupled oxygen plasmas by trace rare gases-optical emission spectroscopy and Langmuir probe analysis Plasma Sources Science and Technology. ,vol. 9, pp. 116- 127 ,(2000) , 10.1088/0963-0252/9/2/304
Iván Camps, Stephen Muhl, Enrique Camps, J.G. Quiñones-Galván, Martín Flores, Tribological properties of TiSiN thin films deposited by laser ablation Surface & Coatings Technology. ,vol. 255, pp. 74- 78 ,(2014) , 10.1016/J.SURFCOAT.2013.12.064