(Methanol-κO)-cis-dioxido{(4Z,N′E)-N′-[(Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]iso­nicotino­hydrazidato}molybdenum(VI)

摘要: In the title complex, [Mo(C16H13N3O2)O2(CH3OH)], deprotonated Schiff base (E)-N′-[(Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]isonicotinohydrazide coordinates in a meridional fashion through enolate O-, imine N- and amidate O-atom donors to Mo atom of cis-[MoO2]2+ core. The sixth coordination site molybdenum is occupied by O methanol mol­ecule. this NO5 sphere adopts distorted octa­hedral geometry. metal shifted 0.335 (1) A from square plane defined three donor atoms ligand one oxide group towards second cis position. crystal, complex forms inversion dimers pair O—H⋯N hydrogen bonds involving –OH pyridine N atom. Additional C—H⋯O contacts stack mol­ecules along b axis.