Sensing of the concentration and enantiomeric excess of chiral compounds with tropos ligand derived metal complexes.
作者： Peng Zhang , Christian Wolf
DOI: 10.1039/C3CC43653E
关键词:
摘要: Palladium(II) complexes carrying chromophoric tropos ligands show a characteristic UV change and strong Cotton effects upon coordination of amino alcohols or diamines. The distinct (chir)optical responses can be used for instantaneous in situ determination the concentration ee diamines at low concentrations.
rsc.org
sci-hub.se 参考文章(44)
Xuefeng Mei, Christian Wolf, A highly congested N,N'-dioxide fluorosensor for enantioselective recognition of chiral hydrogen bond donors. Chemical Communications. pp. 2078- 2079 ,(2004) , 10.1039/B407718K
Sonia Nieto, Vincent M. Lynch, Eric V. Anslyn, Hyunwoo Kim, Jik Chin, Rapid Enantiomeric Excess and Concentration Determination Using Simple Racemic Metal Complexes Organic Letters. ,vol. 10, pp. 5167- 5170 ,(2008) , 10.1021/OL802085J
Marcela M. Wanderley, Cheng Wang, Chuan-De Wu, Wenbin Lin, A Chiral Porous Metal–Organic Framework for Highly Sensitive and Enantioselective Fluorescence Sensing of Amino Alcohols Journal of the American Chemical Society. ,vol. 134, pp. 9050- 9053 ,(2012) , 10.1021/JA302110D
Gilbert E. Tumambac, Christian Wolf, Enantioselective Analysis of an Asymmetric Reaction Using a Chiral Fluorosensor Organic Letters. ,vol. 7, pp. 4045- 4048 ,(2005) , 10.1021/OL0516216
Takeshi Ohkuma, Henri Doucet, Trang Pham, Koichi Mikami, Toshinobu Korenaga, Masahiro Terada, Ryoji Noyori, Asymmetric Activation of Racemic Ruthenium(II) Complexes for Enantioselective Hydrogenation Journal of the American Chemical Society. ,vol. 120, pp. 1086- 1087 ,(1998) , 10.1021/JA972897E
Andrea E. Holmes, Debasis Das, James W. Canary, Chelation-enhanced circular dichroism of tripodal bisporphyrin ligands. Journal of the American Chemical Society. ,vol. 129, pp. 1506- 1507 ,(2007) , 10.1021/JA0666147
Christian Wolf, Keith W. Bentley, Chirality sensing using stereodynamic probes with distinct electronic circular dichroism output Chemical Society Reviews. ,vol. 42, pp. 5408- 5424 ,(2013) , 10.1039/C3CS35498A
Diana Leung, J. Frantz Folmer-Andersen, Vincent M. Lynch, Eric V. Anslyn, Using Enantioselective Indicator Displacement Assays To Determine the Enantiomeric Excess of α-Amino Acids Journal of the American Chemical Society. ,vol. 130, pp. 12318- 12327 ,(2008) , 10.1021/JA803806C
Kohsuke Aikawa, Masafumi Kojima, Koichi Mikami, Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis Angewandte Chemie. ,vol. 48, pp. 6073- 6077 ,(2009) , 10.1002/ANIE.200902084
Diana Leung, Eric V. Anslyn, Transitioning Enantioselective Indicator Displacement Assays for α-Amino Acids to Protocols Amenable to High-Throughput Screening Journal of the American Chemical Society. ,vol. 130, pp. 12328- 12333 ,(2008) , 10.1021/JA8038079