Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−
作者： Lanying Song , Dongdi Zhang , Pengtao Ma , Zhijie Liang , Jingping Wang
DOI: 10.1039/C3CE40343B
关键词:
摘要: Two lanthanide-containing peroxoisopolyanions [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14− (Ln = LaIII; PrIII), have been synthesized by reaction of Na2WO4 and lanthanide (Ln) ions in the presence peroxide. These represent first two examples peroxo-containing Ln-stabilized polyanions (LSPs), highest number W atoms among all known isopolytungstates (IPTs) as well.
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