Three-Dimensional Network Structures Based on Pyridyl-Calix[4]Arene Metal Complexes.
作者： Carmelo Sgarlata , Giovanna Brancatelli , Cosimo G. Fortuna , Domenico Sciotto , Silvano Geremia
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摘要: A new series of supramolecular assemblies is obtained through the interaction 3-pyridylmethyl-calixarenes and copper or zinc ions. The complexes formed are characterized both in solution solid state. results offer appealing insights into how steric crowding lower rim different coordination modes metal centers have a great impact on overall architecture with formation monomeric, dimeric, oligomeric/polymeric species.
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