Oxiranylidene intermediate in the reaction of trans-2-chloro-3- tert-butyloxirane with sodium phenoxide.
作者： Harlan L. Goering , Steven D. Paisley
DOI: 10.1016/S0040-4039(00)84962-X
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摘要: Abstract The reaction of trans-2-chloro-3-(t-butyl)oxirane with sodium phenoxide in acetonitrile to give trans-2-phenoxy-3-(t-butyl)oxirane involves α-elimination an oxiranylidene which undergoes a stereoselective stepwise addition phenol product.
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