Cyclopropanes : XXXIII. Reaction of lithium metal surfaces with optically active 1-halo-1-methyl-2,2-diphenylcyclopropane
作者： H.M. Walborsky , M.S. Aronoff
DOI: 10.1016/S0022-328X(00)93500-9
关键词: Optically active 、 Halo 、 Halide 、 Photochemistry 、 Particle size 、 Racemization 、 Chemistry 、 Lithium 、 Derivative (chemistry) 、 Lithium metal
摘要: Abstract The reaction of lithium metal surfaces with optically active 1-halo-1-methyl-2,2-diphenylcyclopropane leads to the formation corresponding derivative which is partially racemized. amount racemization observed a function halide used (I > Br Cl), sodium content as well its particle size.
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sci-hub.se 参考文章(49)
William Glaze, Robert West, SOLID COMPLEXES OF ALKYLLLITHIUM COMPOUNDS WITH LITHIUM HALIDES1 Journal of the American Chemical Society. ,vol. 82, pp. 4437- 4437 ,(1960) , 10.1021/JA01501A086
J. L. Webb, Charles K. Mann, H. M. Walborsky, Cyclopropanes. XXVI. Electrolytic reduction of optically active 1-halo-1-methyl-2,2-diphenylcyclopropanes Journal of the American Chemical Society. ,vol. 92, pp. 2042- 2051 ,(1970) , 10.1021/JA00710A042
H. M. Walborsky, C. G. Pitt, Cyclopropanes. XIII. The Absolute Configuration of 1-Methyl-2,2-diphenylcyclopropane Journal of the American Chemical Society. ,vol. 84, pp. 4831- 4838 ,(1962) , 10.1021/JA00883A040
Dietmar Seyferth, Lawrence G. Vaughan, The isomeric 1-propenyllithium reagents: their NMR spectra and the stereochemistry of their formation by the direct reaction and by the transmetalation reaction Journal of Organometallic Chemistry. ,vol. 1, pp. 201- 204 ,(1963) , 10.1016/S0022-328X(00)87451-3
E. A. Braude, J. A. Coles, 461. Alkenylation employing lithium alkenyls. Part V. The formation and some reactions of cis-propenyl-lithium Journal of the Chemical Society (Resumed). pp. 2078- 2084 ,(1951) , 10.1039/JR9510002078
Dietmar Seyferth, Harvey M. Cohen, The stability of cyclopropyllithium in diethyl ether and in tetrahydrofuran Journal of Organometallic Chemistry. ,vol. 1, pp. 15- 21 ,(1963) , 10.1016/S0022-328X(00)80040-6
William H. Glaze, Charles M. Selman, Cyclohexylmetal compounds. II. Nuclear magnetic resonance and carbonation results on (+-)-menthyllithium Journal of Organic Chemistry. ,vol. 33, pp. 1987- 1990 ,(1968) , 10.1021/JO01269A062
Gary R. Peyton, William H. Glaze, Bonding properties in organolithium aggregates Theoretical Chemistry Accounts. ,vol. 13, pp. 259- 261 ,(1969) , 10.1007/BF01171767
Rolf Huisgen, Wilhelm Mack, Nucleophile aromatische Substitutionen, XIII. Der Nachweis löslicher Komplexe aus Lithiumpiperidid und Lithiumhalogeniden Chemische Berichte. ,vol. 93, pp. 332- 340 ,(1960) , 10.1002/CBER.19600930210
H.M. Walborsky, M.S. Aronoff, Cyclopropanes XIX. Reaction of lithium metal with optically active halides Journal of Organometallic Chemistry. ,vol. 4, pp. 418- 420 ,(1965) , 10.1016/S0022-328X(00)80336-8