The stability of cyclopropyllithium in diethyl ether and in tetrahydrofuran

作者: Dietmar Seyferth , Harvey M. Cohen

DOI: 10.1016/S0022-328X(00)80040-6

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摘要: The half-life of cyclopropyllithium in diethyl ether is ca. 138 h at room temperature, which roughly equals the stability of n-butyllithium in this solvent and which is far greater than the …

参考文章(10)
Dietmar Seyferth, Hiroshi Yamazaki, David L. Alleston, Stepwise Reduction of gem-Dihalocyclopropanes with Tri-n-butyltin Hydride1 Journal of Organic Chemistry. ,vol. 28, pp. 703- 706 ,(1963) , 10.1021/JO01038A025
Harold. Hart, Romeo A. Cipriani, The Decomposition of Cyclopropaneacetyl Peroxide Journal of the American Chemical Society. ,vol. 84, pp. 3697- 3700 ,(1962) , 10.1021/JA00878A021
H. M. Walborsky, F. M. Hornyak, Cyclopropanes: The Cyclopropyl Carbanion1,2 Journal of the American Chemical Society. ,vol. 77, pp. 6026- 6029 ,(1955) , 10.1021/JA01627A067
HENRY GILMAN, A. H. HAUBEIN, HOWARD HARTZFELD, THE CLEAVAGE OF SOME ETHERS BY ORGANOLITHIUM COMPOUNDS Journal of Organic Chemistry. ,vol. 19, pp. 1034- 1040 ,(1954) , 10.1021/JO01372A007
Paul D. Bartlett, Sidney Friedman, Martin Stiles, THE REACTION OF ISOPROPYLLITHIUM AND t-BUTYLLITHIUM WITH SIMPLE OLEFINS Journal of the American Chemical Society. ,vol. 75, pp. 1771- 1772 ,(1953) , 10.1021/JA01103A541
Vernon A. Slabey, Reaction of Cyclopropyl Chloride with Lithium. Isolation of Dicyclopropyl Journal of the American Chemical Society. ,vol. 74, pp. 4928- 4930 ,(1952) , 10.1021/JA01139A056
HENRY GILMAN, BERNARD J. GAJ, Preparation and Stability of Some Organolithium Compounds in Tetrahydrofuran Journal of Organic Chemistry. ,vol. 22, pp. 1165- 1168 ,(1957) , 10.1021/JO01361A007
Dietmar Seyferth, Michael A. Weiner, The Preparation of Organolithium Compounds by the Transmetalation Reaction. I. Vinyllithium1,2 Journal of the American Chemical Society. ,vol. 83, pp. 3583- 3586 ,(1961) , 10.1021/JA01478A010
Dietmar Seyferth, Harvey M. Cohen, The Preparation of Organolithium Compounds by the Transmetalation Reaction. VI. Cyclopropyllithium Inorganic Chemistry. ,vol. 2, pp. 625- 629 ,(1963) , 10.1021/IC50007A049