Modification of graphene/graphene oxide with polymer brushes using controlled/living radical polymerization

作者: Albert Badri , Michael R. Whittaker , Per B. Zetterlund

DOI: 10.1002/POLA.26094

关键词:

摘要: Graphene nanosheets possess a range of extraordinary physical and electrical properties with enormous potential for applications in microelectronics, photonic devices, nanocomposite materials. However, single graphene platelets tend to undergo agglomeration due strong π–π Van der Waals interactions, which significantly compromises the final material properties. One strategies overcome this problem, increase compatibility receiving polymer host matrix, is modify (or oxide (GO)) brushes. The research date can be grouped into approaches involving grafting-from grafting-to techniques, further relying on covalent or noncovalent attachment chains suitably modified graphene/GO. present Highlight article describes efforts area, focusing use controlled/living radical polymerization techniques. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Chem,

参考文章(99)
P. Taylor, Ostwald ripening in emulsions Advances in Colloid and Interface Science. ,vol. 75, pp. 107- 163 ,(1998) , 10.1016/S0001-8686(98)00035-9
Elena Bekyarova, Mikhail E. Itkis, Palanisamy Ramesh, Claire Berger, Michael Sprinkle, Walt A. de Heer, Robert C. Haddon, Chemical Modification of Epitaxial Graphene: Spontaneous Grafting of Aryl Groups Journal of the American Chemical Society. ,vol. 131, pp. 1336- 1337 ,(2009) , 10.1021/JA8057327
Masami Kamigaito, Tsuyoshi Ando, Mitsuo Sawamoto, Metal-catalyzed living radical polymerization. Chemical Reviews. ,vol. 101, pp. 3689- 3746 ,(2001) , 10.1021/CR9901182
Dmitriy A. Dikin, Richard D. Piner, Rodney S. Ruoff, Inhwa Jung, Tunable electrical conductivity of individual graphene oxide sheets reduced at "low" temperatures. Nano Letters. ,vol. 8, pp. 4283- 4287 ,(2008) , 10.1021/NL8019938
Valérie Sciannamea, Robert Jérôme, Christophe Detrembleur, In-Situ Nitroxide-Mediated Radical Polymerization (NMP) Processes:  Their Understanding and Optimization Chemical Reviews. ,vol. 108, pp. 1104- 1126 ,(2008) , 10.1021/CR0680540
Zhong Jin, Thomas P. McNicholas, Chih-Jen Shih, Qing Hua Wang, Geraldine L. C. Paulus, Andrew J. Hilmer, Steven Shimizu, Michael S. Strano, Click Chemistry on Solution-Dispersed Graphene and Monolayer CVD Graphene Chemistry of Materials. ,vol. 23, pp. 3362- 3370 ,(2011) , 10.1021/CM201131V
Cyrille Boyer, Aurelia Derveaux, Per B. Zetterlund, Michael R. Whittaker, Synthesis of multi-block copolymer stars using a simple iterative Cu(0)-mediated radical polymerization technique Polymer Chemistry. ,vol. 3, pp. 117- 123 ,(2012) , 10.1039/C1PY00384D
Jay R. Lomeda, Condell D. Doyle, Dmitry V. Kosynkin, Wen-Fang Hwang, James M. Tour, Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets Journal of the American Chemical Society. ,vol. 130, pp. 16201- 16206 ,(2008) , 10.1021/JA806499W
Anton Lerf, Heyong He, Michael Forster, Jacek Klinowski, Structure of Graphite Oxide Revisited Journal of Physical Chemistry B. ,vol. 102, pp. 4477- 4482 ,(1998) , 10.1021/JP9731821
Xuan Jiang, Brad M. Rosen, Virgil Percec, Mimicking “nascent” Cu(0) mediated SET‐LRP of methyl acrylate in DMSO leads to complete conversion in several minutes Journal of Polymer Science Part A. ,vol. 48, pp. 403- 409 ,(2010) , 10.1002/POLA.23797