Heptahexaenylidene Complexes:  Synthesis and Characterization of the First Complexes with an MCCCCCCCR2Moiety (M = Cr, W)

作者: Markus Dede , Matthias Drexler , Helmut Fischer

DOI: 10.1021/OM700386T

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摘要: Silica-induced elimination of dimethylamide from [(CO)5M(C⋮C)3C(NMe2)3]- [M = Cr (4a), W (4b)] affords the first isolated and characterized heptahexaenylidene complexes [(CO)5MCCCCCCC(NMe2)2] (5a,b...

参考文章(45)
Slawomir Szafert, Pierre Haquette, Stephen B. Falloon, J.A. Gladysz, Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(η5-C5Me5)Re(NO)(PPh3)(CCCCCAr2)]+BF4− (CAr2=9-fluorenylidene) Journal of Organometallic Chemistry. ,vol. 604, pp. 52- 58 ,(2000) , 10.1016/S0022-328X(00)00201-1
Michael I. Bruce, Peter Hinterding, Edward R.T. Tiekink, Brian W. Skelton, Allan H. White, Cyclopentadienyl-ruthenium and -osmium chemistry Journal of Organometallic Chemistry. ,vol. 450, pp. 209- 218 ,(1993) , 10.1016/0022-328X(93)80159-9
Nazzareno Re, Antonio Sgamellotti, Carlo Floriani, Density Functional Study of Metallacumulene Complexes Organometallics. ,vol. 19, pp. 1115- 1122 ,(2000) , 10.1021/OM990824T
Willi Kantlehner, Erwin Haug, Walter W. Mergen, Peter Speh, Thomas Maier, Joanis J. Kapassakalidis, H. J. Bräuner, Helmut Hagen, Ein Herstellungsverfahren für N,N,N′, N′,N″,N″ - Hexaalkylguanidinium-chloride Synthesis. ,vol. 1983, pp. 904- 905 ,(1983) , 10.1055/S-1983-30558
Jeffrey R. Lomprey, John P. Selegue, Syntheses and structures of two trifluoroacetate-trapped derivatives of a ruthenium butatrienylidene complex Organometallics. ,vol. 12, pp. 616- 617 ,(1993) , 10.1021/OM00027A008
Michael I. Bruce, Benjamin G. Ellis, Brian W. Skelton, Allan H. White, Further chemistry of ruthenium butatrienylidene complexes Journal of Organometallic Chemistry. ,vol. 690, pp. 1772- 1783 ,(2005) , 10.1016/J.JORGANCHEM.2005.01.035