Oxalate Oxidase Model Studies – Substrate Reactivity
作者： Piotr L. Pawlak , Manashi Panda , Jia Li , Atanu Banerjee , Derek J. Averill
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摘要: The synthesis and structure of [MnLCl]0.5H2O (1·0.5H2O, HL = 1-benzyl-4-acetato-1,4,7-triazacyclononane) is reported. Complex 1 exists as a coordination polymer in the solid state, MnII center bonded to three amine nitrogen atoms, one carboxylate oxygen atom, chlorido ligand, an adjacent group chelating fashion afford seven-coordinate center. dissolution acetonitrile containing excess oxalate (ox) ions results monomeric species. When mixtures are exposed under ambient conditions, dark pink EPR-silent species generated. believed be [MnIII(ox)2]–, which from displacement ligand L– by ion. decomposition this ultimately formation equiv. CO2 per ion consumed, HCO3– ion, Further reaction resulting with presence leads additional degradation.
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sci-hub.se 参考文章(53)
Hibbard E. Williams, Theodore R. Wandzilak, Oxalate synthesis, transport and the hyperoxaluric syndromes. The Journal of Urology. ,vol. 141, pp. 742- 747 ,(1989) , 10.1016/S0022-5347(17)40999-2
Jim M. Dunwell, Richard W. Pickersgill, Eui-Jeon Woo, Peter W. Goodenough, Allison C. Marvier, Germin is a manganese containing homohexamer with oxalate oxidase and superoxide dismutase activities. Nature Structural & Molecular Biology. ,vol. 7, pp. 1036- 1040 ,(2000) , 10.1038/80954
Mei M. Whittaker, Heng-Yen Pan, Erik T. Yukl, James W. Whittaker, Burst Kinetics and Redox Transformations of the Active Site Manganese Ion in Oxalate Oxidase IMPLICATIONS FOR THE CATALYTIC MECHANISM Journal of Biological Chemistry. ,vol. 282, pp. 7011- 7023 ,(2007) , 10.1074/JBC.M609374200
Stephen C. Cheng, Christine A. Blaine, Michael G. Hill, Kent R. Mann, Electrochemical and IR Spectroelectrochemical Studies of the Electrocatalytic Reduction of Carbon Dioxide by [Ir2(dimen)4]2+(dimen = 1,8-Diisocyanomenthane) Inorganic Chemistry. ,vol. 35, pp. 7704- 7708 ,(1996) , 10.1021/IC9512385
Angela Altomare, Maria Cristina Burla, Mercedes Camalli, Giovanni Luca Cascarano, Carmelo Giacovazzo, Antonietta Guagliardi, Anna Grazia Giuseppina Moliterni, Giampiero Polidori, Riccardo Spagna, SIR97: a new tool for crystal structure determination and refinement Journal of Applied Crystallography. ,vol. 32, pp. 115- 119 ,(1999) , 10.1107/S0021889898007717
Mark A. Suwyn, Randall E. Hamm, Mechanism of oxidation oxalate with trans-1,2-diaminocyclohexanetetraacetatomanganate(III) in aqueous solution Inorganic Chemistry. ,vol. 6, pp. 142- 145 ,(1967) , 10.1021/IC50047A033
Domenick F. Leto, Timothy A. Jackson, Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes Journal of Biological Inorganic Chemistry. ,vol. 19, pp. 1- 15 ,(2014) , 10.1007/S00775-013-1067-4
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Victor Marcelino, Mauro Micheloni, Piero Paoletti, Paola Paoli, Heptacoordination of manganese(II) by the polyazacycloalkane 1,4,7,10,13,16,19-heptaazacycloheneicosane, [21]aneN7. Crystal structure of the [Mn([21]aneN7)](ClO4)2 solid compound and thermodynamics of complexation in water solution Inorganic Chemistry. ,vol. 29, pp. 1716- 1718 ,(1990) , 10.1021/IC00334A025
Navamoney Arulsamy, Joergen Glerup, Derek J. Hodgson, Mononuclear Iron(II), Manganese(II), and Nickel(II) and Tetranuclear Iron(III) Complexes of a New Hexadentate Ligand Inorganic Chemistry. ,vol. 33, pp. 3043- 3050 ,(1994) , 10.1021/IC00092A006
Tomasz Borowski, Arianna Bassan, Nigel G. J. Richards, Per E. M. Siegbahn, Catalytic Reaction Mechanism of Oxalate Oxidase (Germin). A Hybrid DFT Study Journal of Chemical Theory and Computation. ,vol. 1, pp. 686- 693 ,(2005) , 10.1021/CT050041R