Crystallization and spectroscopic properties in Er3+ doped oxyfluorogermanate glass ceramics containing Na

作者: Yuebo Hu , Sawei Qiu , Yuan Gao , Jianbei Qiu

DOI: 10.1016/J.OPTMAT.2015.03.014

关键词:

摘要: Abstract The Er3+ doped oxyfluorogermanate glasses, with a composition containing Na element, were synthesized by the conventional melting–quenching technique. When element was introduced into of glass, crystals behavior investigated in details. Depending on annealing procedure supplied, thermal precursor glasses system GeO2/BaF2/AlF3/Na2O/NaF/ZnO/GdF3/ErF3 led to precipitation different crystal phase nanocrystals. It confirmed nanocrystals GC600 is orthorhombic NaBaAlF6 which enhance obviously UC luminescence Er3+. However, G585 decrease luminescence, indicated few Er ions enter lattice this nanocrystal phase. reason emission intensity GC585 analyzed.

参考文章(28)
Chunyan Cao, Weiping Qin, Jisen Zhang, Study on up-conversion emissions of Yb3+/Tm3+ co-doped GdF3 and NaGdF4 Optics Communications. ,vol. 283, pp. 547- 550 ,(2010) , 10.1016/J.OPTCOM.2009.10.097
R. Balda, A. Oleaga, J. Fernández, J.M. Fdez-Navarro, Spectroscopy and frequency upconversion of Er3+ ions in lead niobium germanate glasses Optical Materials. ,vol. 24, pp. 83- 90 ,(2003) , 10.1016/S0925-3467(03)00109-5
Gongxun Bai, Lili Tao, Kefeng Li, Lili Hu, Yuen Hong Tsang, Enhanced ~ 2 μm and upconversion emission from Ho–Yb codoped oxyfluoride glass ceramics Journal of Non-crystalline Solids. ,vol. 361, pp. 13- 16 ,(2013) , 10.1016/J.JNONCRYSOL.2012.10.012
Shilong Zhao, Shiqing Xu, Guohua Jia, Degang Deng, Lihui Huang, Huanping Wang, Er3+/Yb3+ codoped oxyfluoride borosilicate glass ceramic containing NaYF4 nanocrystals for amorphous silicon solar cells Materials Letters. ,vol. 65, pp. 2407- 2409 ,(2011) , 10.1016/J.MATLET.2011.04.084
Daqin Chen, Yuansheng Wang, Yunlong Yu, En Ma, Feng Liu, Fluorescence and Judd–Ofelt analysis of Nd3+ ions in oxyfluoride glass ceramics containing CaF2 nanocrystals Journal of Physics and Chemistry of Solids. ,vol. 68, pp. 193- 200 ,(2007) , 10.1016/J.JPCS.2006.10.009
Xvsheng Qiao, Xianping Fan, Minquan Wang, Luminescence behavior of Er3+ in glass ceramics containing BaF2 nanocrystals Scripta Materialia. ,vol. 55, pp. 211- 214 ,(2006) , 10.1016/J.SCRIPTAMAT.2006.04.023
R. E. Thoma, H. Insley, G. M. Hebert, The Sodium Fluoride-Lanthanide Trifluoride Systems Inorganic Chemistry. ,vol. 5, pp. 1222- 1229 ,(1966) , 10.1021/IC50041A032
J.F. Suyver, J. Grimm, K.W. Krämer, H.U. Güdel, Highly efficient near-infrared to visible up-conversion process in Journal of Luminescence. ,vol. 114, pp. 53- 59 ,(2005) , 10.1016/J.JLUMIN.2004.11.012
XiaoMan Li, Hai Guo, YunLe Wei, YanRong Guo, Hang Lu, Hyeon Mi Noh, Jung Hyun Jeong, Enhanced up-conversion in Er3+-doped transparent glass-ceramics containing NaYbF4 nanocrystals Journal of Luminescence. ,vol. 152, pp. 168- 171 ,(2014) , 10.1016/J.JLUMIN.2013.11.042