Panchromatic Response in Solid‐State Dye‐Sensitized Solar Cells Containing Phosphorescent Energy Relay Dyes

作者: Jun-Ho Yum , Brian E. Hardin , Soo-Jin Moon , Etienne Baranoff , Frank Nüesch

DOI: 10.1002/ANIE.200904725

关键词:

摘要: Running relay: Incorporating an energy-relay dye (ERD) into the hole transporter of a dye-sensitized solar cell increased power-conversion efficiency by 29 % extending light harvesting blue region. In operating mechanism (see picture), absorption red photons sensitizer transfers electron TiO2 and electrolyte. Blue absorbed ERD are transferred FRET to sensitizer.

参考文章(27)
U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissörtel, J. Salbeck, H. Spreitzer, M. Grätzel, Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies Nature. ,vol. 395, pp. 583- 585 ,(1998) , 10.1038/26936
Brian E. Hardin, Eric T. Hoke, Paul B. Armstrong, Jun-Ho Yum, Pascal Comte, Tomás Torres, Jean M. J. Fréchet, Md Khaja Nazeeruddin, Michael Grätzel, Michael D. McGehee, Increased light harvesting in dye-sensitized solar cells with energy relay dyes Nature Photonics. ,vol. 3, pp. 406- 411 ,(2009) , 10.1038/NPHOTON.2009.96
C. Siegers, B. Olàh, U. Würfel, J. Hohl-Ebinger, A. Hinsch, R. Haag, Donor-acceptor-functionalized polymers for efficient light harvesting in the dye solar cell Solar Energy Materials and Solar Cells. ,vol. 93, pp. 552- 563 ,(2009) , 10.1016/J.SOLMAT.2008.11.038
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Jürgen Hagen, Winfried Schaffrath, Peter Otschik, Ralf Fink, Andreas Bacher, Hans-Werner Schmidt, Dietrich Haarer, Novel hybrid solar cells consisting of inorganic nanoparticles and an organic hole transport material Synthetic Metals. ,vol. 89, pp. 215- 220 ,(1997) , 10.1016/S0379-6779(97)81221-0
K Tennakone, G R R A Kumara, A R Kumarasinghe, K G U Wijayantha, P M Sirimanne, A dye-sensitized nano-porous solid-state photovoltaic cell Semiconductor Science and Technology. ,vol. 10, pp. 1689- 1693 ,(1995) , 10.1088/0268-1242/10/12/020
Ute B. Cappel, Elizabeth A. Gibson, Anders Hagfeldt, Gerrit Boschloo, Dye regeneration by spiro-MeOTAD in solid state dye-sensitized solar cells studied by photoinduced absorption spectroscopy and spectroelectrochemistry. Journal of Physical Chemistry C. ,vol. 113, pp. 6275- 6281 ,(2009) , 10.1021/JP811196H
R. J. Watts, G. A. Crosby, Quantum efficiencies of transition metal complexes. III. Effect of ligand substituents on radiatiive and radiationless processes Journal of the American Chemical Society. ,vol. 94, pp. 2606- 2614 ,(1972) , 10.1021/JA00763A007
Yoshimoto Abe, Sadaharu Suga, Hironori Arakawa, Kazuhiro Sayama, Shingo Tsukagoshi, Tohru Mori, Kohjiro Hara, Yasuyo Ohga, Akira Shinpou, Efficient sensitization of nanocrystalline TiO2 films with cyanine and merocyanine organic dyes Solar Energy Materials and Solar Cells. ,vol. 80, pp. 47- 71 ,(2003) , 10.1016/S0927-0248(03)00113-2
Lukas Schmidt-Mende, Shaik M. Zakeeruddin, Michael Grätzel, Efficiency improvement in solid-state-dye-sensitized photovoltaics with an amphiphilic Ruthenium-dye Applied Physics Letters. ,vol. 86, pp. 013504- ,(2005) , 10.1063/1.1844032