Ionic Limiting Molar Conductivity Calculation of Li-Ion Battery Electrolyte Based on Mode Coupling Theory
作者： Xiangming He , Weihua Pu , Han , Jian Chen , Jiufang Lu
DOI: 10.1021/JP055233X
关键词:
摘要: A method is proposed based on mode coupling theory in which the ion transference number introduced into theory. The ionic limiting molar conductivities of LiPF6, LiClO4, LiBF4, LiCF3SO3, Li(CF3SO3)2N, LiC4F9SO3, and LiAsF6 PC(propylene carbonate), GBL(gamma-butyrolactone), carbonate)/EMC(ethylmethyl carbonate)/DME(dimethoxyethane) are calculated this method, does not involve any adjustable parameter. results fit well to literature data by an empirically adjusted formula. This presents a potential way calculate Li-ion battery electrolytes.
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