Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
作者： Ramesh Giri , Nathan Maugel , Bruce M. Foxman , Jin-Quan Yu
DOI: 10.1021/OM8000444
关键词:
摘要: Pd(OAc)2-mediated dehydrogenation of an alkyl group to a double bond or η3-allylic complex via sp3 C−H activation and allylic oxidation is reported. A novel redox proposed for this under oxidant-free conditions. catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed cyclopentylcarboxamides.
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