Enhancement of nutrient recovery from microalgae in hydrothermal liquefaction using activated carbon

作者: Chihiro Fushimi , Mai Kakimura , Ryo Tomita , Akihito Umeda , Tsuyoshi Tanaka

DOI: 10.1016/J.FUPROC.2016.03.006

关键词:

摘要: Abstract For large-scale biofuel production from microalgae, the following outcomes are needed to reduce environmental impact and cost 1) extraction of a large amount lipid (bio-oil), 2) recovery almost all nutrients their reuse for cultivation, 3) effective utilization solid residue (char). We investigated possibility using activated carbon enhance bio-oil in hydrothermal liquefaction (HTL). Microalga Fistulifera solaris was reacted at 573 K 10 MPa 0–60 min with or without commercial (0.5–5.0 wt.% microalgae) an autoclave reactor. Results show 0.5 wt.% can substantially promote total nitrogen aqueous phase, probably because catalytic effect on decarboxylation reactions produce amines. Larger (> 1.0 wt.%) decreasd due adsorption. A kinetic study phase showed apparent reaction order 3 rates were 1.1 × 10 − 7  s − 1 5.6 × 10 − 8 carbon, respectively. has insignificant influence phosphorus recovery.

参考文章(47)
Mitsufumi Matsumoto, Shigeki Mayama, Michiko Nemoto, Yorikane Fukuda, Masaki Muto, Tomoko Yoshino, Tadashi Matsunaga, Tsuyoshi Tanaka, Morphological and molecular phylogenetic analysis of the high triglyceride‐producing marine diatom, Fistulifera solaris sp. nov. (Bacillariophyceae) Phycological Research. ,vol. 62, pp. 257- 268 ,(2014) , 10.1111/PRE.12066
Peter J. Valdez, Vincent J. Tocco, Phillip E. Savage, A general kinetic model for the hydrothermal liquefaction of microalgae. Bioresource Technology. ,vol. 163, pp. 123- 127 ,(2014) , 10.1016/J.BIORTECH.2014.04.013
Armando T. Quitain, Nobuaki Sato, Hiroyuki Daimon, Koichi Fujie, Production of valuable materials by hydrothermal treatment of shrimp shells Industrial & Engineering Chemistry Research. ,vol. 40, pp. 5885- 5888 ,(2001) , 10.1021/IE010439F
Diego López Barreiro, Wolter Prins, Frederik Ronsse, Wim Brilman, Hydrothermal liquefaction (HTL) of microalgae for biofuel production: State of the art review and future prospects Biomass & Bioenergy. ,vol. 53, pp. 113- 127 ,(2013) , 10.1016/J.BIOMBIOE.2012.12.029
Laura Garcia Alba, Cristian Torri, Chiara Samorì, Jaapjan van der Spek, Daniele Fabbri, Sascha R. A. Kersten, Derk W. F. (Wim) Brilman, Hydrothermal Treatment (HTT) of Microalgae: Evaluation of the Process As Conversion Method in an Algae Biorefinery Concept Energy & Fuels. ,vol. 26, pp. 642- 657 ,(2012) , 10.1021/EF201415S
Man Kee Lam, Keat Teong Lee, Abdul Rahman Mohamed, Current status and challenges on microalgae-based carbon capture. International Journal of Greenhouse Gas Control. ,vol. 10, pp. 456- 469 ,(2012) , 10.1016/J.IJGGC.2012.07.010
Bing Hu, Aimin Shi, Xiaochen Ma, Yanling Cheng, Paul Chen, Yuhuan Liu, Xiangyang Lin, Roger Ruan, Zhenyi Du, Cultivation of a microalga Chlorella vulgaris using recycled aqueous phase nutrients from hydrothermal carbonization process Bioresource Technology. ,vol. 126, pp. 354- 357 ,(2012) , 10.1016/J.BIORTECH.2012.09.062
Hakan Demiral, İlknur Demiral, Belgin Karabacakoğlu, Fatma Tümsek, Production of activated carbon from olive bagasse by physical activation Chemical Engineering Research and Design. ,vol. 89, pp. 206- 213 ,(2011) , 10.1016/J.CHERD.2010.05.005