Phase equilibria in the REFeB system at 1000 °C

作者: M.Uma Devi , K.P Gupta

DOI: 10.1016/0022-5088(90)90127-6

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摘要: Abstract Phase equilibria in the REFeB system (where RE represents total rare earth content of Indian Misch metal) at 1000 °C has been investigated ironrich side, up to about 40 at.% and 45 B, using metallography, X-ray diffraction thermomagnetic analysis techniques. The isothermal section shows presence two ternary intermediate phases which have identified as RE2Fe14B (Γ) REFe4B4 (Δ) phases. At iron end, a b.c.c. α phase found. Fe2B (β) practically no solubility RE. Γ appears very limited solid solubility. Both Δ are tetragonal with lattice parameters = 8.784 A , c 12.177 7.106 17.011 respectively. Curie temperature 245 Ms ≈ 120 e.m.u. g−1. also magnetic transition between 240 440 °C.

参考文章(11)
W. Gong, G. C. Hadjipanayis, Misch‐metal‐iron based magnets Journal of Applied Physics. ,vol. 63, pp. 3513- 3515 ,(1988) , 10.1063/1.340726
K.H.J. Buschow, D.B. De Mooij, J.L.C. Daams, H.M. Van Noort, Phase relationships, magnetic and crystallographic properties of NdFeB alloys Journal of The Less Common Metals. ,vol. 115, pp. 357- 366 ,(1986) , 10.1016/0022-5088(86)90159-1
K.H.J. Buschow, New permanent magnet materials Materials Science Reports. ,vol. 1, pp. 1- 63 ,(1986) , 10.1016/0920-2307(86)90003-4
C. Abache, H. Oesterreicher, Magnetic properties of compounds R2Fe14B Journal of Applied Physics. ,vol. 57, pp. 4112- 4114 ,(1985) , 10.1063/1.334635
M. Sagawa, S. Fujimura, N. Togawa, H. Yamamoto, Y. Matsuura, New material for permanent magnets on a base of Nd and Fe (invited) Journal of Applied Physics. ,vol. 55, pp. 2083- 2087 ,(1984) , 10.1063/1.333572
D. Niarchos, G. Zouganelis, A. Kostikas, A. Simopoulos, Magnetic properties of the R1+eFe4B4 compounds (R = rare earth) from magnetization and Mössbauer measurements Solid State Communications. ,vol. 59, pp. 389- 391 ,(1986) , 10.1016/0038-1098(86)90569-7
H.R. Rechenberg, J.P. Sanchez, Effective magnetic fields on Fe in R1+εFe4B4 alloys Solid State Communications. ,vol. 62, pp. 461- 464 ,(1987) , 10.1016/0038-1098(87)91098-2
J. J. Croat, J. F. Herbst, R. W. Lee, F. E. Pinkerton, Pr‐Fe and Nd‐Fe‐based materials: A new class of high‐performance permanent magnets (invited) Journal of Applied Physics. ,vol. 55, pp. 2078- 2082 ,(1984) , 10.1063/1.333571
H.F. Braun, J. Muller, K. Yvon, A. Bezinge, Tetragonal rare earth (R) Iron borides, R1+εFe4B4 (ε≅0.1), with incommensurate rare earth and iron substructures Solid State Communications. ,vol. 55, pp. 131- 135 ,(1985) , 10.1016/0038-1098(85)90264-9
E. B. Boltich, E. Oswald, M. Q. Huang, S. Hirosawa, W. E. Wallace, E. Burzo, Magnetic characteristics of R2Fe14B systems prepared with high purity rare earths (R=Ce, Pr, Dy, and Er) Journal of Applied Physics. ,vol. 57, pp. 4106- 4108 ,(1985) , 10.1063/1.334633