Macrocycles and Cation Selectivity

作者: David E. Fenton

DOI: 10.1007/978-94-009-9035-7_21

关键词:

摘要: The selectivity patterns for ionophorous agents, cyclic polyethers, cryptands and related model compounds are presented discussed. factors which influence these sequences elucidated, it is shown that whilst cavity control critical selectivity, also necessary to introduce flexibility into the ligand in order obtain transfer. application of cation chemical synthesis illustrated by reference template macrocyclic Schiff bases.

参考文章(15)
W. Simon, W. E. Morf, P. Ch. Meier, Specificity for alkali and alkaline earth cations of synthetic and natural organic complexing agents in membranes Springer, Berlin, Heidelberg. pp. 113- 160 ,(1973) , 10.1007/BFB0004366
Jean-Marie Lehn, Design of organic complexing agents Strategies towards properties Springer, Berlin, Heidelberg. pp. 1- 69 ,(1973) , 10.1007/BFB0004364
E. Edward Bittar, Membranes and ion transport ,(1970)
Hans K. Frensdorff, Stability constants of cyclic polyether complexes with univalent cations Journal of the American Chemical Society. ,vol. 93, pp. 600- 606 ,(1971) , 10.1021/JA00732A007
Richard M. Noyes, Thermodynamics of Ion Hydration as a Measure of Effective Dielectric Properties of Water Journal of the American Chemical Society. ,vol. 84, pp. 513- 522 ,(1962) , 10.1021/JA00863A002
D.G. Parsons, M.R. Truter, J.N. Wingfield, Alkali metal tetraphenylborate complexes with some macrocyclic, “Crown”, polyethers Inorganica Chimica Acta. ,vol. 14, pp. 45- 48 ,(1975) , 10.1016/S0020-1693(00)85720-5
David G. Parsons, Synthesis of bridged macrocyclic polyethers of high complexing ability with group 1a salts Journal of the Chemical Society, Perkin Transactions 1. ,vol. 9, pp. 451- 455 ,(1978) , 10.1039/P19780000451
P.R. Danesi, R. Chiarizia, M. Pizzichini, A. Saltelli, Transfer rate of K+ ions from aqueous picrate solutions into 1,2 dichloroethane solutions of the macrocyclic polyether dibenzo-18-crown-6 Journal of Inorganic and Nuclear Chemistry. ,vol. 40, pp. 1119- 1123 ,(1978) , 10.1016/0022-1902(78)80521-1
Katarina Neupert-Laves, Max Dobler, The Crystal Structure of the NH4NCS Complex of Nonactin Helvetica Chimica Acta. ,vol. 59, pp. 614- 623 ,(1976) , 10.1002/HLCA.19760590225