Self-catalyzed chemical vapor deposition method for the growth of device-quality metal thin films

作者: N. Bahlawane , P. Antony Premkumar , K. Onwuka , G. Reiss , K. Kohse-Höinghaus

DOI: 10.1016/J.MEE.2007.05.014

关键词:

摘要: Deposition of metals and alloys was demonstrated using thermal chemical vapor deposition starting from commercially available precursors in the absence molecular hydrogen. The adopted strategy relies solely on selective reactivity alcohols with metal complexes at temperature. In this report, particular interest given to growth nickel silver. This process allows optimization single hcp fcc phases Ni(acac)"2, whereas several silver allow crystalline structure Steady kinetics, without incubation time, noticed for all investigated precursors. electrical conductivity hcp-Ni, fcc-Ni fcc-Ag shows typical decay bulk value increased film thickness, temperature resistivity coefficients are similar corresponding material.

参考文章(18)
T. Kada, M. Ishikawa, H. Machida, A. Ogura, Y. Ohshita, K. Soai, Volatile CVD precursor for Ni film: cyclopentadienylallylnickel Journal of Crystal Growth. ,vol. 275, ,(2005) , 10.1016/J.JCRYSGRO.2004.11.198
Dennis A. Edwards, Mary F. Mahon, Kieran C. Molloy, Virginie Ogrodnik, Aerosol-assisted chemical vapour deposition of silver films from adducts of functionalised silver carboxylates Journal of Materials Chemistry. ,vol. 13, pp. 563- 570 ,(2003) , 10.1039/B210085C
P.A. Premkumar, N. Bahlawane, G. Reiss, K. Kohse-Höinghaus, CVD of Metals Using Alcohols and Metal Acetylacetonates, Part II: Role of Solvent and Characterization of Metal Films Made by Pulsed Spray Evaporation CVD Chemical Vapor Deposition. ,vol. 13, pp. 227- 231 ,(2007) , 10.1002/CVDE.200606573
J SHEN, W SHAN, Y ZHANG, J DU, H XU, K FAN, W SHEN, Y TANG, Gas-phase selective oxidation of alcohols: In situ electrolytic nano-silver/zeolite film/copper grid catalyst Journal of Catalysis. ,vol. 237, pp. 94- 101 ,(2006) , 10.1016/J.JCAT.2005.10.027
K. C. Hewitt, P. A. Casey, R. J. Sanderson, M. A. White, R. Sun, High-throughput resistivity apparatus for thin-film combinatorial libraries Review of Scientific Instruments. ,vol. 76, pp. 093906- ,(2005) , 10.1063/1.2037947
Mikko Utriainen, Minna Kröger-Laukkanen, Leena-Sisko Johansson, Lauri Niinistö, Studies of metallic thin film growth in an atomic layer epitaxy reactor using M(acac)2 (M = Ni, cu, Pt) precursors Applied Surface Science. ,vol. 157, pp. 151- 158 ,(2000) , 10.1016/S0169-4332(99)00562-0
Hyungsoo Choi, Sungho Park, Tae Hyung Kim, Novel Nickel Precursors for Chemical Vapor Deposition Chemistry of Materials. ,vol. 15, pp. 3735- 3738 ,(2003) , 10.1021/CM034210X
L. Gao, P. Härter, Ch. Linsmeier, A. Wiltner, R. Emling, D. Schmitt-Landsiedel, Silver metal organic chemical vapor deposition for advanced silver metallization Microelectronic Engineering. ,vol. 82, pp. 296- 300 ,(2005) , 10.1016/J.MEE.2005.07.078
T. Maruyama, T. Tago, Nickel thin films prepared by chemical vapour deposition from nickel acetylacetonate Journal of Materials Science. ,vol. 28, pp. 5345- 5348 ,(1993) , 10.1007/BF00570088