Silver metal organic chemical vapor deposition for advanced silver metallization

作者: L. Gao , P. Härter , Ch. Linsmeier , A. Wiltner , R. Emling

DOI: 10.1016/J.MEE.2005.07.078

关键词: Substrate (electronics)Deposition (phase transition)Thin filmChemical vapor depositionMetalorganic vapour phase epitaxyNanotechnologyLayer (electronics)Materials scienceTinChemical engineeringMetallizing

摘要: The use of silver interconnects enables higher speed for silicon integrated circuits. formation Ag requires sequential deposition a continuous barrier layer followed by and chemical-mechanical polishing (CMP). In this article, various organometallic precursors (hfac)Ag(1,5-COD), (fod)Ag(PEt"3) (hfac)Ag(VTES) the metal organic chemical vapor (MOCVD) on TiN adhesion were evaluated their characteristics was studied. It confirmed that could be deposited at substrate temperature as low 180^oC with (hfac)Ag(VTES). thin film precursor vaporization 50^oC 220-250^oC, resulting in resistivity around 1.8-2.0@m@Wcm.

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