Syntheses, characterizations and crystal structures of two lead(II) phosphonate–sulfonate hybrid materials
作者： Jun-Ling Song , Chong Lei , Yan-Qiong Sun , Jiang-Gao Mao
DOI: 10.1016/J.JSSC.2004.03.037
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摘要: Abstract Hydrothermal reactions of lead(II) acetate with 5-sulfoisophthalic acid monosodium salt (NaH2BTS) and N-(phosphonomethyl)-N-methylglycine, MeN(CH2CO2H)(CH2PO3H2) (H3L1), or a new aminodiphosphonic acid, 3-Pyridyl-CH2N(CH2PO3H2)2 (H4L2), afforded two novel phosphonate–sulfonate hybrids, namely, Pb3[L1][BTS][H2O]·H2O 1 Pb2[HL3][BTS]·H2O 2 (H2L3=3-Pyridyl-CH2(Me)N(CH2PO3H2)). H2L3 was formed as result the decomposition one phosphonate group in H4L2 during reaction. Compound crystallizes triclinic space P a=9.9148(4) A, b=10.4382(4) A, c=10.6926(2) A, α=96.495(2)°, β=110.599(2)°, γ=98.433(2)°, V=1008.31(6) A3, Z=2. The structure compound features 3D network built from interconnection hexanuclear Pb6(L1)2 units 1D double chains carboxylate–sulfonate. monoclinic P21/c a=9.5403(7) A, b=11.6170(8) A, c=19.7351(15) A, β=97.918(2)°, V=2166.4(3) A3, Z=4. has by cross-linkage phosphonates 2D layers
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sci-hub.se 参考文章(39)
Jean-Marie Lehn, JL Atwood, JED Davies, DD MacNicol, F Vögtle, Comprehensive Supramolecular Chemistry ,(1996)
Li-Min Zheng, Ping Yin, Xin, Novel Coordination Polymer Containing a Mixed Valence Copper(I,II) Phosphonate Unit: CuI2CuII(hedpH2)2(4,4‘-bpy)2·2H2O (hedp = 1-Hydroxyethylidenediphosphonate) Inorganic Chemistry. ,vol. 41, pp. 4084- 4086 ,(2002) , 10.1021/IC015631O
Jin Zhu, Xianhui Bu, Pingyun Feng, Galen D. Stucky, An Open-Framework Material with Dangling Organic Functional Groups in 24-Ring Channels Journal of the American Chemical Society. ,vol. 122, pp. 11563- 11564 ,(2000) , 10.1021/JA002118L
EW Stein Sr, A Clearfield, MA Subramanian, Conductivity of group IV metal sulfophosphonates and a new class of interstratified metal amine-sulfophosphonates Solid State Ionics. ,vol. 83, pp. 113- 124 ,(1996) , 10.1016/0167-2738(95)00215-4
Elisabeth Irran, Thomas Bein, Norbert Stock, Inorganic–organic hybrid materials: synthesis and crystal structure determination from powder diffraction data of Pb2(O3PCH2C6H4CH2PO3) Journal of Solid State Chemistry. ,vol. 173, pp. 293- 298 ,(2003) , 10.1016/S0022-4596(03)00085-9
Chong Lei, Jiang-Gao Mao, Yan-Qiong Sun, Hui-Yi Zeng, Abraham Clearfield, [Zn6[MeN(CH2CO2)(CH2PO3)](6)(Zn)]4- anion: the first example of the oxo-bridged Zn6 octahedron with a centered Zn(II) cation. Inorganic Chemistry. ,vol. 42, pp. 6157- 6159 ,(2003) , 10.1021/IC034137C
Myriam Riou-Cavellec, Morgane Sanselme, Nathalie Guillou, Gérard Férey, Hydrothermal synthesis and ab initio structural resolution from X-ray powder diffraction of a new open framework Cu(II) carboxyethylphosphonate: Na[Cu(O3P-(CH2)2-CO2)]. Inorganic Chemistry. ,vol. 40, pp. 723- 725 ,(2001) , 10.1021/IC000758J
Ewa Gałdecka, Zdzislaw Gałdecki, Paula Gawryszewska, Janina Legendziewicz, Structure of a novel polynuclear europium compound with N-phosphonomethylglycine: heptaaquaperchloratodi-μ4-N-phosphonomethylglycine-dieuropium(III) triperchlorate monohydrate, [Eu2(HO3PCH2NH2CH2CO2)2(H2O)7(ClO4)]·3ClO4·H2O New Journal of Chemistry. ,vol. 24, pp. 387- 391 ,(2000) , 10.1039/B000230P
Myriam Riou-Cavellec, Morgane Sanselme, Gérard Férey, Hybrid open frameworks: synthesis, structure and thermal behaviour of MIL-26, a new three-dimensional vanadium(IV) ethylcarboxyphosphonate Na[VIVO(O3P(CH2)2CO2)]·2H2O Journal of Materials Chemistry. ,vol. 10, pp. 745- 748 ,(2000) , 10.1039/A909870D
Brian Adair, Srinivasan Natarajan, Anthony K. Cheetham, Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4) Journal of Materials Chemistry. ,vol. 8, pp. 1477- 1479 ,(1998) , 10.1039/A800488I