Determination of Solvent Systems for Blade Coating Thin Film Photovoltaics
作者： Jeffrey G. Tait , Tamara Merckx , Wenqi Li , Cindy Wong , Robert Gehlhaar
关键词:
摘要: With lab-scale solution-processed thin fi lm photovoltaic (TFPV) devices attaining market relevant effi ciencies, the demand for environmentally friendly and scalable deposition techniques is increasing. Replacing toxic halogenated solvents a priority industrialization of TFPV. In this work, generalized ve-step process presented fabricating high-performance from nonhalogenated inks. Resulting process, several new solvent systems are introduced based on thiophene, tetralin, 1,2,4-trimethylbenzene, o -xylene, anisole blade coating three different diketopyrrolopyrrole-based (pDPP5T-2, pPDPP5T-2S, P390) bulk heterojunctions applied in organic devices. Devices pDPP5T-2S P390 attain 5.6% 6.1% ciency, respectively, greater than ciency either material reached when processed system commonly used. These processes implemented without post-deposition annealing treatments or additives. The Hansen solubility parameters pDPP5T-2 obtained, used, along with wettability data variety substrates, to determine optimum combinations ratios deposition. This results pathways materials.
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sci-hub.se 参考文章(33)
Robert D. Deegan, Olgica Bakajin, Todd F. Dupont, Greb Huber, Sidney R. Nagel, Thomas A. Witten, Capillary flow as the cause of ring stains from dried liquid drops Nature. ,vol. 389, pp. 827- 829 ,(1997) , 10.1038/39827
Alexander Lange, Wolfram Schindler, Michael Wegener, Konstantinos Fostiropoulos, Silvia Janietz, Inkjet printed solar cell active layers prepared from chlorine-free solvent systems Solar Energy Materials and Solar Cells. ,vol. 109, pp. 104- 110 ,(2013) , 10.1016/J.SOLMAT.2012.10.011
Yu-Han Chang, Shin-Rong Tseng, Chun-Yu Chen, Hsin-Fei Meng, En-Chen Chen, Sheng-Fu Horng, Chian-Shu Hsu, None, Polymer solar cell by blade coating Organic Electronics. ,vol. 10, pp. 741- 746 ,(2009) , 10.1016/J.ORGEL.2009.03.001
Kazuya Tada, Mitsuyoshi Onoda, Poor man's green bulk heterojunction photocells: A chlorine-free solvent for poly(3-hexylthiophene)/C60 composites Solar Energy Materials and Solar Cells. ,vol. 100, pp. 246- 250 ,(2012) , 10.1016/J.SOLMAT.2012.01.026
Benjamin Schmidt-Hansberg, Monamie Sanyal, Michael F. G. Klein, Marina Pfaff, Natalie Schnabel, Stefan Jaiser, Alexei Vorobiev, Erich Müller, Alexander Colsmann, Philip Scharfer, Dagmar Gerthsen, Uli Lemmer, Esther Barrena, Wilhelm Schabel, Moving through the phase diagram: morphology formation in solution cast polymer-fullerene blend films for organic solar cells. ACS Nano. ,vol. 5, pp. 8579- 8590 ,(2011) , 10.1021/NN2036279
Ning Li, Derya Baran, Karen Forberich, Florian Machui, Tayebeh Ameri, Mathieu Turbiez, Miguel Carrasco-Orozco, Martin Drees, Antonio Facchetti, Frederik C Krebs, Christoph J Brabec, None, Towards 15% energy conversion efficiency: a systematic study of the solution-processed organic tandem solar cells based on commercially available materials Energy and Environmental Science. ,vol. 6, pp. 3407- 3413 ,(2013) , 10.1039/C3EE42307G
Badrou Réda Aïch, Serge Beaupré, Mario Leclerc, Ye Tao, Highly efficient thieno[3,4-c]pyrrole-4,6-dione-based solar cells processed from non-chlorinated solvent Organic Electronics. ,vol. 15, pp. 543- 548 ,(2014) , 10.1016/J.ORGEL.2013.12.012
Frederik C. Krebs, Fabrication and processing of polymer solar cells: A review of printing and coating techniques Solar Energy Materials and Solar Cells. ,vol. 93, pp. 394- 412 ,(2009) , 10.1016/J.SOLMAT.2008.10.004
Choong-Do Park, Trever A. Fleetham, Jian Li, Bryan D. Vogt, High performance bulk-heterojunction organic solar cells fabricated with non-halogenated solvent processing Organic Electronics. ,vol. 12, pp. 1465- 1470 ,(2011) , 10.1016/J.ORGEL.2011.05.020
Florian Machui, Stefan Langner, Xiangdong Zhu, Steven Abbott, Christoph J Brabec, None, Determination of the P3HT:PCBM solubility parameters via a binary solvent gradient method: Impact of solubility on the photovoltaic performance Solar Energy Materials and Solar Cells. ,vol. 100, pp. 138- 146 ,(2012) , 10.1016/J.SOLMAT.2012.01.005