Enthalpy of Dilution of Aqueous [C4mim][Gly] at 298.15 K

作者: Wei Guan , Wei-Feng Xue , San-ping Chen , Da-Wei Fang , Yan Huang

DOI: 10.1021/JE8009539

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摘要: A novel amino acid ionic liquid [C4mim][Gly] (1-butyl-3-methylimidazolium glycine) was prepared by a neutralization method. The molar enthalpies of dilution, ΔDHm(mi→mf), aqueous at various molalities were measured (298.15 ± 0.01) K. values the apparent relative enthalpy, φL, calculated using both extended Debye−Huckel equation and Pitzer equation, which in good agreement within experimental error. In terms solution [C4mim][Gly], ΔsHm, estimated. estimated ΔsHm consistent with previously obtained.

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