Terminal Chalcogenido Complexes of Gallium Supported by Tris(3,5-di-tert-butylpyrazolyl)hydroborato Ligation: [TpBut2]GaE (E = Se, Te)
作者： Matthew C. Kuchta , Gerard Parkin
DOI: 10.1021/IC970208U
关键词:
摘要: Terminal selenido and tellurido complexes of gallium supported by the tris(3,5-di-tert-butylpyrazolyl)hydroborato ligand, [TpBut2]GaE (E = Se, Te), have been prepared oxidative addition elemental chalcogens to three-coordinate gallium(I) complex [TpBut2]Ga. The positions equilibria involving chalcogenido transfer between [TpBut2]M (M Ga, In) Et3PSe demonstrate that strengths X≈Se interactions decrease in sequence [TpBut2]GaSe > [TpBut2]InSe.
acs.org
sci-hub.se 参考文章(0)