CDW evidence in one-dimensional K0.3MoO3 by means of Raman scattering

作者: G. Travaglini , I. Mörke , P. Wachter

DOI: 10.1016/0038-1098(83)90483-0

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摘要: Abstract Raman scattering measurements on the one-dimensional (1-D) blue bronze K0.3MoO3 are reported as function of temperature. At about 50 cm-1 a line Ag(A) symmetry was found with an anomalous temperature dependence. The symmetry, softening eigenfrequency and apparent disappearing coupling constant at critical temperature, allow us to assign this amplitude mode CDW, predicted by theory Peierls transition. A precursor room also observed is discussed.

参考文章(9)
J. Graham, A. D. Wadsley, The crystal structure of the blue potassium molybdenum bronze, K0.28MoO3 Acta Crystallographica. ,vol. 20, pp. 93- 100 ,(1966) , 10.1107/S0365110X66000173
D. Pines, P. Nozieres, Noel Corngold, The theory of quantum liquids American Journal of Physics. ,vol. 36, pp. 279- 280 ,(1968) , 10.1119/1.1974502
G. Travaglini, P. Wachter, J. Marcus, C. Schlenker, The blue bronze K0.3MoO3: A new one-dimensional conductor Solid State Communications. ,vol. 37, pp. 599- 603 ,(1981) , 10.1016/0038-1098(81)90143-5
E.F. Steigmeier, R. Loudon, G. Harbeke, H. Auderset, G. Scheiber, Raman scattering in K2Pt(CN)4Br0.3 · 3H2O Solid State Communications. ,vol. 17, pp. 1447- 1452 ,(1975) , 10.1016/0038-1098(75)90623-7
M.J. Rice, S. Strässler, Theory of the soft phonon mode and dielectric constant below the Peierls transition temperature Solid State Communications. ,vol. 13, pp. 1931- 1933 ,(1973) , 10.1016/0038-1098(73)90003-3
R. E. Peierls, Louis D. Roberts, Quantum theory of solids Physics Today. ,vol. 9, pp. 29- 29 ,(1956) , 10.1063/1.3059963