Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis
作者： Koon-Kee Kow , Kamaliah Sirat
DOI: 10.1016/J.CCLET.2015.05.049
关键词:
摘要: Abstract Type IV deep eutectic solvent (DES) involves the formation of metal-based eutectics from metal salts or salt hydrate in combination with various hydrogen-bond donors (HBDs) such as urea, ethylene glycol acetamide. In current study, two distinguished approaches were used to synthesize potential DESs, given direct heating and evaporating methods. Successful synthesized DESs subjected for physical properties characterization by Fourier Transform Infrared (FTIR) Spectroscopy, thermal stability, viscosity, conductivity analyses. Five novel manganese (II)-based successfully reported this study. Data obtained indicated that MnCl2·4H2O·acetamide DES exhibits lowest freezing point (27.5 °C), highest stability (193 °C dehydration), viscosity (ŋ = 112.8 cP) (0.12723 mS/cm). The findings reveal characteristics, nature features industrial solvents.
imm.ac.cn参考文章(37)
John Christopher Barron, The electrochemistry of Zn in deep eutectic solvents University of Leicester. ,(2010)
Ken A. Dill, Sarina Bromberg, Dirk Stigter, Molecular Driving Forces : Statistical Thermodynamics in Biology, Chemistry, Physics, and Nanoscience Garland Science. ,(2010) , 10.4324/9780203809075
Peter Wasserscheid, Thomas Welton, Ionic Liquids in Synthesis ,(2002)
Y HU, Physical and electrochemical properties of new binary room-temperature molten salt electrolyte based on LiBETI and acetamide Solid State Ionics. ,vol. 175, pp. 277- 280 ,(2004) , 10.1016/J.SSI.2003.11.038
R. Mrozek, Z. Rzączyńska, M. Sikorska-Iwan, THERMAL ANALYSIS OF MANGANESE(II) COMPLEXES WITH GLYCINE Journal of Thermal Analysis and Calorimetry. ,vol. 63, pp. 839- 846 ,(2001) , 10.1023/A:1010164709840
Qinghua Zhang, Karine De Oliveira Vigier, Sébastien Royer, François Jérôme, Deep eutectic solvents: syntheses, properties and applications Chemical Society Reviews. ,vol. 41, pp. 7108- 7146 ,(2012) , 10.1039/C2CS35178A
X Ge, CD Gu, XL Wang, JP Tu, None, Endowing manganese oxide with fast adsorption ability through controlling the manganese carbonate precursor assembled in ionic liquid. joint international conference on information sciences. ,vol. 438, pp. 149- 158 ,(2015) , 10.1016/J.JCIS.2014.09.029
Maan Hayyan, Farouq S. Mjalli, Mohd Ali Hashim, Inas M. AlNashef, Xue Mei Tan, Electrochemical reduction of dioxygen in Bis (trifluoromethylsulfonyl) imide based ionic liquids Journal of Electroanalytical Chemistry. ,vol. 657, pp. 150- 157 ,(2011) , 10.1016/J.JELECHEM.2011.04.008
Hua Zhao, Gary A. Baker, Shaletha Holmes, New eutectic ionic liquids for lipase activation and enzymatic preparation of biodiesel Organic and Biomolecular Chemistry. ,vol. 9, pp. 1908- 1916 ,(2011) , 10.1039/C0OB01011A
Huaiyou Wang, Yan Jing, Xiaohua Wang, Ying Yao, Yongzhong Jia, Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride Journal of Molecular Liquids. ,vol. 170, pp. 20- 24 ,(2012) , 10.1016/J.MOLLIQ.2012.03.017