Luminescence and Magnetic Properties of Tb(III) Complexes with TETA and Synergistic Effect by 1,10-Phenanthroline
作者： Jung-Soo Kang , Kam Tong Leung , Hyung-Kook Cho , Jun-Gill Kang , Youngku Sohn
DOI: 10.1002/BKCS.10889
关键词:
摘要: Two Tb(III) complexes, [Tb(TETA)]− and [Tb(TETA)(phen)]− (TETA = 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate phen = 1,10-phenanthroline), were synthesized their luminescence ( 5D4 → 7F J =0–6 transitions) magnetic properties examined. The photoluminescence (PL) quantum yield of (Q = 0.47) was significantly higher than that (Q = 0.006). dramatic increase (78×) in green attributed to intramolecular energy transfer from phen Tb(III). rate according Dexter theory found be approximately 1011 s−1. temperature dependence the molar susceptibilities confirmed two complexes behave as paramagnets obeying Curie–Weiss law. In addition, field-dependent magnetization measured −70 + 70 kOe range at T = 1.8 K fitted well with Brillouin function following values: g eff = 1.5, μ B = 9.27 × 10−21 emu, J = 6. These results provide new insights into development lanthanide metal tetraaza © 2016 Korean Chemical Society, Seoul & Wiley-VCH Verlag GmbH Co. KGaA, Weinheimmacrocyclic ligands.
sci-hub.se 参考文章(57)
Seungwon Lee, Sungeun Jang, Jun-Gill Kang, Youngku Sohn, Luminescent Eu(III) and Tb(III) activator ions in La(OH)3 and La2O3 nanowire matrices Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 201, pp. 35- 44 ,(2015) , 10.1016/J.MSEB.2015.08.004
Lorenzo Tei, Alessandro Barge, Matteo Galli, Roberta Pinalli, Luciano Lattuada, Eliana Gianolio, Silvio Aime, Polyhydroxylated GdDTPA-derivatives as high relaxivity magnetic resonance imaging contrast agents RSC Advances. ,vol. 5, pp. 74734- 74743 ,(2015) , 10.1039/C5RA15071J
Michael A. Bruckman, Lauren N. Randolph, Neetu M. Gulati, Phoebe L. Stewart, Nicole F. Steinmetz, Silica-coated Gd(DOTA)-loaded protein nanoparticles enable magnetic resonance imaging of macrophages. Journal of Materials Chemistry B. ,vol. 3, pp. 7503- 7510 ,(2015) , 10.1039/C5TB01014D
Youngku Sohn, Structural and spectroscopic characteristics of terbium hydroxide/oxide nanorods and plates Ceramics International. ,vol. 40, pp. 13803- 13811 ,(2014) , 10.1016/J.CERAMINT.2014.05.096
Hong-Mei Zhang, Yuan-Chun He, Jin Yang, Ying-Ying Liu, Jian-Fang Ma, Ten Coordination Polymers Constructed Using an Unprecedented Azamacrocyclic Octacarboxylate Ligand 1,4,8,11-Tetrazacyclododecane-N,N′,N″,N‴-Tetra-Methylene-Isophthalic Acid: Syntheses, Structures, and Photoluminescent Properties Crystal Growth & Design. ,vol. 14, pp. 2307- 2317 ,(2014) , 10.1021/CG500003U
Xiandong Zhu, Zhen Ma, Wenhua Bi, Yuling Wang, Daqiang Yuan, Rong Cao, Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines CrystEngComm. ,vol. 10, pp. 19- 22 ,(2008) , 10.1039/B710633E
Katie L. Peterson, Jonathan V. Dang, Evan A. Weitz, Cutler Lewandowski, Valérie C. Pierre, Effect of lanthanide complex structure on cell viability and association. Inorganic Chemistry. ,vol. 53, pp. 6013- 6021 ,(2014) , 10.1021/IC500282N
Angelo J. Amoroso, Simon J. A. Pope, Using lanthanide ions in molecular bioimaging Chemical Society Reviews. ,vol. 44, pp. 4723- 4742 ,(2015) , 10.1039/C4CS00293H
Won Joo Kim, Jin Seog Gwag, Jun-Gill Kang, Youngku Sohn, Photoluminescence imaging of Eu(III), Eu(III)/Ag, Eu(III)/Tb(III), and Eu(III)/Tb(III)/Ag-doped Gd(OH)3 and Gd2O3 nanorods Ceramics International. ,vol. 40, pp. 12035- 12044 ,(2014) , 10.1016/J.CERAMINT.2014.04.043
Jun-Gill Kang, Yongkwang Jung, Bong-Ki Min, Youngku Sohn, Full characterization of Eu(OH) 3 and Eu 2 O 3 nanorods Applied Surface Science. ,vol. 314, pp. 158- 165 ,(2014) , 10.1016/J.APSUSC.2014.06.165